Polymorphism in 3-Pyridylsydnone: Preparative and Structural Aspects
Paul V. Bernhardt A B , David Kvaskoff A , Rakesh Naduvile Veedu A and Curt Wentrup A B
+ Author Affiliations
- Author Affiliations
A School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Qld 4072, Australia.
B Corresponding authors. Email: p.bernhardt@uq.edu.au; wentrup@uq.edu.au
Australian Journal of Chemistry 65(4) 376-380 https://doi.org/10.1071/CH12041
Submitted: 24 January 2012 Accepted: 1 March 2012 Published: 2 April 2012
Abstract
Two polymorphs of 3-(3′-pyridyl)sydnone 4 have been investigated. It was established that the metastable P2/c form is the kinetically favoured product formed by recrystallization from solution, but this may be converted to the new, more stable, P21/c polymorph by sublimation or heating in the solid state.
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