Free Standard AU & NZ Shipping For All Book Orders Over $80!
Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Shopping Cart: ( empty )
You are here: Home > Journals > CH > CH05247
RESEARCH ARTICLE
Contents Vol 59(9)

Heteropolymetallic Supramolecular Solid-State Architectures Constructed from Dicyanoaurate Ion, Phen, and 3d Metals

Gong-Feng Xu A , Zhan-Quan Liu A B , Hui-Bo Zhou A , Yang Guo A and Dai-Zheng Liao A
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Nankai University, Tianjin 300071, China.

B Corresponding author. Email: coord@nankai.edu.cn

Australian Journal of Chemistry 59(9) 640-646 https://doi.org/10.1071/CH05247
Submitted: 7 September 2005  Accepted: 13 September 2006   Published: 19 October 2006

Abstract

Two new supramolecular polymeric coordination complexes, {Zn(phen)2[Au2(CN)4](H2O)}·1.5H2O 1 and {Mn(phen)[Au2(CN)4](H2O)}·PriOH 2, have been obtained through a self-assembly process. The three-dimensional supramolecular architectures of compounds 1 and 2 are sustained by aurophilic, hydrogen-bonding, and/or π–π interactions. Gold atoms linked with aurophilic bonds arrange in a pattern not frequently observed.


Acknowledgments

This work was supported by the National Natural Science Foundation of China (no. 20071019, 90501002, 20331010), the Natural Science Foundation of Tianjin (no. 043602211), and the Natural Science Key Foundation of Tianjin.


References


[1]   O. M. Yaghi, H. L. Li, C. Davis, D. Richardson, T. L. Groy, Acc. Chem. Res. 1998, 31,  474.
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |   and references therein.
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
         
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |   and references therein.
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
        | Crossref |  GoogleScholarGoogle Scholar |  
         
        | Crossref |  GoogleScholarGoogle Scholar |  open url image1

[50]   G. M. Sheldrick, SHELXS-97 and SHELXL-97 1997 (Siemens AXI: Madison, WI).