PETROLEUM GENERATION AND SOURCE ROCK ASSESSMENT IN TERRIGENOUS SEQUENCES: AN UPDATE

Abstract

Analytical pyrolysis and sealed tube pyrolysis at low temperatures have been used to study the timing and petroleum generating capacity of selected Permian through Tertiary coals and carbonaceous shales in relation to their petrographic and elemental composition. The results show that judicious application of flash pyrolysis techniques in conjunction with more conventional procedures are essential for effective source rock assessment in terrigenous source rocks, particularly in those of lower quality.

Although the petroleum potential of the samples follows the broad trends in petrographic composition established for Australian coals, that is, relative proportions of vitrinite, inertinite and liptinite, there is much variation which cannot be explained petrographically at the maceral group level. Furthermore, there is no simple relationship between pyrolytic hydrocarbon yield from terrigenous kerogens and overall elemental composition. The yield and composition of pyrolysable normal hydrocarbons varies widely depending on the nature and amount of liptinite macerals, particularly for samples with Hydrogen Indices below 300. Liptinite-poor (<10 per cent) samples may yield significant amounts of hydrocarbons, but typically they have a low wax content. Suberinite is associated with high yields of waxy hydrocarbons, but sporinite and liptodetrinite have a lower hydrocarbon potential and do not yield the waxy compounds. These geochemical results are explicable in terms of the relatively abstract concepts of labile, refractory and inert kerogens rather than standard petrographic descriptions.

Mass balance calculations based on Rock-Eval analyses of samples from the Jurassic Walloon Coal Measures show that the maximum oil formation occurs over a very narrow maturation window from 0.8 to 1.0 per cent Ro, although small amounts of oil may be generated at lower maturation levels. The gas to oil ratio of the generated hydrocarbons is constant up to a reflectance level of 1.0 per cent Ro, where upon the proportion of gas increases rapidly. The low quality Permian source rocks from the Cooper Basin have a lower ratio of labile to refractory kerogen than the Jurassic and Tertiary examples. As a result, the gas to oil ratio of hydrocarbons formed in the oil window is higher and the oil potential appears to be exhausted at an earlier stage of maturation. Efficient migration of hydrocarbons from Permian sediments in the Cooper Basin also appears to occur at a relatively early stage of maturation compared with the Jurassic Walloon Coal Measures.