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Environmental Chemistry Environmental Chemistry Society
Environmental problems - Chemical approaches
Table of Contents
Environmental Chemistry

Environmental Chemistry

Volume 15 Number 8 2018

EN18154Using laboratory incubations to predict the fate of pharmaceuticals in aquatic ecosystems

Johan Fahlman 0000-0002-3242-2668, Jerker Fick, Jan Karlsson, Micael Jonsson, Tomas Brodin and Jonatan Klaminder
pp. 463-471

Environmental context. Environmental persistence of excreted pharmaceuticals in aquatic ecosystems is usually predicted using small-scale laboratory experiments assumed to simulate natural conditions. We studied five pharmaceuticals comparing their removal rates from water under laboratory conditions and under natural environmental conditions existing in a large pond. We found that the laboratory conditions did not fully capture the complexity within the pond, which led to different removal rates in the two systems.

EN18156Sorptive remediation of perfluorooctanoic acid (PFOA) using mixed mineral and graphene/carbon-based materials

Supriya Lath 0000-0001-5174-9685, Divina A. Navarro, Dusan Losic, Anupama Kumar and Michael J. McLaughlin
pp. 472-480

Environmental context. Per- and poly-fluoroalkyl substances (PFASs) are contaminants of emerging concern, creating a need to develop efficient multi-functional adsorbents for improved remediation performance. By exploiting the versatility of graphene technology, we demonstrate that combining mineral and carbonaceous phases greatly increases and strengthens PFAS-binding to the adsorbent. The study highlights the benefits and potential applications of mixed adsorbents in PFAS-remediation.

EN18146Biofuel ash addition increases ectomycorrhizal fungal exudation in pure culture

Ana Paola Vilches 0000-0002-9557-3367, Sara H. Norström, Madelen A. Olofsson, Petra Fransson and Dan Bylund
pp. 481-492

Environmental context. Spreading recycled wood ash in forests may counteract acidification and nutrient losses, but the process may also affect symbiotic fungi in these eco-systems. We show how fungal species react when exposed to ash solutions; for example, by an increased release of organic acids and other compounds. These effects can influence pH and metal availability in forest soils treated with ash.

EN18101Development of an analytical method for the simultaneous determination of the 17 EU Watch List compounds in surface waters: a Spanish case study

José Luis Malvar, Concepción Abril, Julia Martín, Juan Luis Santos 0000-0001-9704-1316, Irene Aparicio, Carmelo Escot, Ana Basanta and Esteban Alonso
pp. 493-505

Environmental context. In 2015, the European Union issued a Watch List of organic pollutants resulting from anthropogenic activities. A major obstacle to controlling these pollutants in the environment is the difficulty of their simultaneous measurement at low concentrations. We developed an analytical method for the simultaneous determination in surface water of the 17 pollutants included in the EU Watch List.

EN18115Biosorption of residual cisplatin, carboplatin and oxaliplatin antineoplastic drugs in urine after chemotherapy treatment

Karel Folens 0000-0002-4692-8037, Alebel Abebe 0000-0003-4138-6467, Jingyue Tang 0000-0003-4848-8511, Frederik Ronsse 0000-0002-3290-9177 and Gijs Du Laing 0000-0001-6661-1312
pp. 506-512

Environmental context. Platinum complexes are widely used to treat cancer; however, these compounds are also rapidly excreted in the urine of patients and can therefore enter waterways, presenting a toxic hazard to the environment. The biopolymer chitosan was found to be an effective and fast adsorbent for capturing multiple platinum complexes currently applied in medicine. This new approach using biomaterials is proposed to treat such drug residues while at the same time recovering the valuable metal from urine.

EN18120Synchrotron infrared microspectroscopy reveals the response of Sphagnum cell wall material to its aqueous chemical environment

Ewen Silvester 0000-0001-8467-7657, Annaleise R. Klein, Kerry L. Whitworth, Ljiljana Puskar and Mark J. Tobin
pp. 513-521

Environmental context. Sphagnum moss is a widespread species in peatlands globally and responsible for a large fraction of carbon storage in these systems. We used synchrotron infrared microspectroscopy to characterise the acid-base properties of Sphagnum moss and the conditions under which calcium uptake can occur (essential for plant tissue integrity). The work allows a chemical model for Sphagnum distribution in the landscape to be proposed.

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