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Environmental Chemistry Environmental Chemistry Society
Environmental problems - Chemical approaches

Volume 20 Number 4 2023

EN23057A review of inorganic contaminants in Australian marine mammals, birds and turtles

Chad V. Jarolimek, Josh J. King, Simon C. Apte 0000-0003-2427-413X, Jane Hall 0000-0001-9310-5140, Anil Gautam, Megan Gillmore and Christopher Doyle
pp. 147-170

Environmental context. Metal concentrations can build up to potentially harmful levels in marine mammals as they are at the top of the food chain. This review summarises the information available on metal concentrations in marine mammals, birds and turtles from around Australia. Despite large data gaps, the available data suggest that metal concentrations are similar to those encountered in other regions of the world.

EN23022Iron dissolution and speciation from combustion particles under environmentally relevant conditions

Cecily Szady 0009-0006-3360-3168, Grace Picarillo 0009-0007-0782-161X, Emily J. Davis 0000-0001-6867-7745, Donata Drapanauskaite, Kristina Buneviciene, Jonas Baltrusaitis 0000-0001-5634-955X and Juan G. Navea 0000-0002-7723-6033
pp. 171-182

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Environmental context. Iron-containing combustion particles are likely to contribute to environmental iron deposition, while atmospheric acidic processing of such particles can promote their dissolution. Here we report the surface-mediated dissolution of iron from ashes generated by biomass burning power plants and kilns. Examination of the dissolution process at several environmentally relevant pHs, suggests that pH has little impact on the fraction of bioavailable Fe(II) that dissolves into the aqueous phase, although Fe(III) is heavily pH dependent.

EN23041Cellular uptake and biotransformation of arsenate by freshwater phytoplankton under salinity gradient revealed by single-cell ICP-MS and CT-HG-AAS

Md Shah Alam 0009-0004-0162-2802, Shogo Fujisawa, Masahiko Zuka, Yinghan Zai, Asami S. Mashio, Ismail M. M. Rahman, Kuo H. Wong and Hiroshi Hasegawa
pp. 183-195

Environmental context. Freshwater phytoplankton are involved in the biogeochemical cycling of arsenic within aquatic ecosystems via uptake processes. Rather than determining the mean arsenic content in a population of freshwater phytoplankton, we investigate the heterogeneity of arsenic uptake by single-cell ICP-MS. Our data show that arsenic distribution within a cell population may be highly heterogeneous, measured at the femtogram per cell level, and are affected by species and salinity.

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