The reaction rate and residual value in southern New South Wales of 12 commercial liming materials from around Australia
M. K. Conyers
A * , B. J. Scott A , M. G. Whitten B and G. J. Poile A
+ Author Affiliations
- Author Affiliations
A NSW Department of Primary Industries, Agricultural Research Institute, PMB, Wagga Wagga, NSW 2650, Australia (Retired).
B The former Department of Soil Science & Plant Nutrition, The University of Western Australia, Perth, WA 6009, Australia (Retired).
Crop & Pasture Science 73(9) 1056-1069 https://doi.org/10.1071/CP21723
Submitted: 19 October 2021 Accepted: 20 January 2022 Published: 19 April 2022
© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing
Abstract
Context: Farmers and consultants are faced with selecting from amongst competing liming materials.
Aim: We sought to establish guidelines for the efficient use of competing liming materials.
Method: The effectiveness of 12 commercial liming materials from around Australia in increasing soil pH, their rate of movement below the depth of incorporation and their residual value to grain yield were measured in our field study.
Key results: Chemical composition (equivalent CaCO3 content) was a major determinant of effectiveness over the longer term. There appeared to be no value to grain yield in the provision of additional Mg above what was already in the soil at this site. Finer commercial products were more effective in the short term and no less effective in the longer term, indicating that fineness also remains a major determinant of effectiveness. The effect of the source of the liming product was a minor determinant of effectiveness. As previously found, there was a tardiness in the reaction rate of dolomites and a slight advantage in the reaction rate of softer limestones but as with fineness, the data for different sources tended to converge over 6–7 years.
Conclusion: All liming materials provided a benefit to grain yield over the 7 years and that benefit was proportional to the material’s chemical purity and fineness.
Implication: Growers and advisers can select the best value for cost amongst the commercially available products at a given geographical location. The quantitative assessment of chemical composition and particle size remains the best means of assessment over both the short and longer terms.
Keywords: calcium, limestone, magnesium, residual carbonate, soil acidification, soil acidity, soil pH, unreacted limestone.
References
Azam G, Gazey C (2021) Slow movement of alkali from surface-applied lime warrants the introduction of strategic tillage for rapid amelioration of subsurface acidity in south-western Australia. Soil Research 59, 97–106.| Slow movement of alkali from surface-applied lime warrants the introduction of strategic tillage for rapid amelioration of subsurface acidity in south-western Australia.Crossref | GoogleScholarGoogle Scholar |
Barber SA (1984) Liming materials and practices. In ‘Soil acidity and liming’. Vol. 12. Agronomy monographs. (Ed. F Adams) pp. 171–209. (ASA, CSSA, SSSA: Madison, WI, USA)
Beacher RL, Longnecker D, Merkle FG (1952) Influence of form, fineness and amount of limestone on plant development and certain soil characteristics. Soil Science 73, 75–82.
| Influence of form, fineness and amount of limestone on plant development and certain soil characteristics.Crossref | GoogleScholarGoogle Scholar |
Brunauer G, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. Journal of the American Chemical Society 60, 309–319.
| Adsorption of gases in multimolecular layers.Crossref | GoogleScholarGoogle Scholar |
Chou L, Garrels RM, Wollast R (1989) Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals. Chemical Geology 78, 269–282.
| Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals.Crossref | GoogleScholarGoogle Scholar |
Conyers MK (2006) Liming and lime materials. In ‘Encyclopedia of soil science’. (Ed. R Lal) pp. 796–798. (Marcel Dekker: New York, NY, USA)
Conyers MK, Scott BJ, Fisher R, Lill W (1996) Predicting the field performance of twelve commercial liming materials from southern Australia. Fertilizer Research 44, 151–161.
| Predicting the field performance of twelve commercial liming materials from southern Australia.Crossref | GoogleScholarGoogle Scholar |
Conyers MK, Mullen CL, Scott BJ, Poile GJ, Braysher BD (2003) Long-Term benefits of limestone applications to soil properties and to cereal crop yields in southern and central New South Wales. Australian Journal of Experimental Agriculture 43, 71–78.
Conyers MK, Scott BJ, Whitten MG (2020) The reaction rate and residual value of particle size fractions of limestone in southern New South Wales. Crop & Pasture Science 71, 368–378.
| The reaction rate and residual value of particle size fractions of limestone in southern New South Wales.Crossref | GoogleScholarGoogle Scholar |
Cregan PD, Hirth JR, Conyers MK (1989) Amelioration of soil acidity by liming and other amendments. In ‘Soil acidity and plant growth’. (Ed. AD Robson) pp. 205–264. (Academic Press: Sydney, NSW)
Doner HE, Lynn WC (1977) Carbonate, halide, sulfate and sulfide minerals. In ‘Minerals in soil environments’. (Eds JB Dixon, SB Weed) pp. 75–98. (SSSA: Madison, WI, USA)
FAO-UNESCO (1974) ‘FAO-UNESCO soil map of the world. Vol. 1 Legend’. (UNESCO: Paris, France)
Jones JD, Mallarino AP (2018) Influence of source and particle size on agricultural limestone efficiency at increasing soil pH. Soil Science Society of America Journal 82, 271–282.
| Influence of source and particle size on agricultural limestone efficiency at increasing soil pH.Crossref | GoogleScholarGoogle Scholar |
Gillman GP, Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils. Australian Journal of Soil Research 24, 61–66.
| Modification to the compulsive exchange method for measuring exchange characteristics of soils.Crossref | GoogleScholarGoogle Scholar |
Haby VA, Leonard AT (2002) Limestone quality and effectiveness for neutralizing soil acidity. Communications in Soil Science and Plant Analysis 33, 2935–2948.
| Limestone quality and effectiveness for neutralizing soil acidity.Crossref | GoogleScholarGoogle Scholar |
Hassett JJ, Jurinak JJ (1971) Effect of Mg2+ ion on the solubility of solid carbonates. Soil Science Society of America Journal 35, 403–406.
| Effect of Mg2+ ion on the solubility of solid carbonates.Crossref | GoogleScholarGoogle Scholar |
Isbell RF (1996) ‘The Australian soil classification’. (CSIRO Publishing: Melbourne, Vic.)
Li GD, Conyers MK, Helyar KR, Lisle CJ, Poile GJ, Cullis BR (2019) Long-term surface application of lime ameliorates subsurface soil acidity in the mixed farming zone of south-eastern Australia. Geoderma 338, 236–246.
| Long-term surface application of lime ameliorates subsurface soil acidity in the mixed farming zone of south-eastern Australia.Crossref | GoogleScholarGoogle Scholar |
Lindsay WL (1979) ‘Chemical equilibria in soils’, (Blackburn Press: New Jersey, USA)
Lipar M, Webb JA (2014) Middle-late Pleistocene and Holocene chronostratigraphy and depositional history of the Tamala Limestone, Cooloongup and Safety Bay Sands, Nambung National Park, southwestern Western Australia. Australian Journal of Earth Sciences 61, 1023–1039.
| Middle-late Pleistocene and Holocene chronostratigraphy and depositional history of the Tamala Limestone, Cooloongup and Safety Bay Sands, Nambung National Park, southwestern Western Australia.Crossref | GoogleScholarGoogle Scholar |
Martin AE, Reeve R (1955) A rapid manometric method for determining soil carbonate. Soil Science 79, 187–197.
| A rapid manometric method for determining soil carbonate.Crossref | GoogleScholarGoogle Scholar |
Merry RH, Hodge TJV, Lewis DC, Jacka J (1995) Evaluation of liming materials used in South Australia. In ‘Plant soil interactions at low pH: principles and management’. (Eds RA Date, NJ Grundon, GE Rayment et al.) pp. 497–503. (Kluwer Academic Publishers: Netherlands)
| Crossref |
Meyer TA, Volk GW (1952) Effect of particle size of limestone on soil reaction, exchangeable cations and plant growth. Soil Science 73, 37–52.
| Effect of particle size of limestone on soil reaction, exchangeable cations and plant growth.Crossref | GoogleScholarGoogle Scholar |
Northcote KH (1979) ‘A factual key for the recognition of Australian soils’, 4th edn. (Rellim Technical Publications: Adelaide, SA, Australia)
Putnis CV, Ruiz-Agudo E, Hövelmann J (2014) Coupled fluctuations in element release during dolomite dissolution. Mineralogical Magazine 78, 1355–1362.
| Coupled fluctuations in element release during dolomite dissolution.Crossref | GoogleScholarGoogle Scholar |
Rayment GE, Lyons DL (2011) ‘Soil chemical methods – Australasia’, (CSIRO Publishing: Melbourne, Vic.)
Scott BJ, Conyers MK, Fisher R, Lill W (1992) Particle size determines the efficiency of calcitic limestone in amending acidic soil. Australian Journal of Agricultural Research 43, 1175–1185.
| Particle size determines the efficiency of calcitic limestone in amending acidic soil.Crossref | GoogleScholarGoogle Scholar |
Scott BJ, Ridley AM, Conyers MK (2000) Management of soil acidity in long-term pastures of south-eastern Australia: a review. Australian Journal of Experimental Agriculture 40, 1173–1198.
| Management of soil acidity in long-term pastures of south-eastern Australia: a review.Crossref | GoogleScholarGoogle Scholar |
Soil Survey Staff (1975) ‘Soil taxonomy: a basic system of soil classification for making and interpreting soil surveys’. USDA soil conservation service. Agriculture Handbook No. 436. p. 754. (US Government Printer: Washington, DC, USA)
Stace HCJ, Hubble GD, Brewer R, Northcote KH, Sleeman JR, Mulcahy MJ, Hallsworth EG (1968) ‘A handbook of Australian soils’. (Rellim Technical Publications: Glenside, South Australia)
Stumm W, Morgan JJ (1996) ‘Aquatic chemistry: chemical equilibria and rates in natural waters’. (John Wiley and Sons Inc.: New York, NY, USA)
Systat Software Inc. (2017) ‘SigmaPlot 14’, (Systat Software Inc.: San Jose, CA, USA)
Vimpany IA, Holford ICR, Milham PJ, Abbott TS (1985) Soil testing service – methods and interpretation. Department of Agriculture New South Wales, Rydalmere.
Whitten M (2002) Amelioration and prevention of agriculturally generated subsurface acidity in sandy soils in Western Australia. PhD Thesis, School of Earth and Geographical Sciences, University of Western Australia, WA, Australia.
Whitten MG, Wong MTF, Rate AW (2000) Amelioration of subsurface acidity in the south-west of Western Australia: downward movement and mass balance of surface-incorporated lime after 2–15 years. Australian Journal of Soil Research 38, 711–728.
| Amelioration of subsurface acidity in the south-west of Western Australia: downward movement and mass balance of surface-incorporated lime after 2–15 years.Crossref | GoogleScholarGoogle Scholar |
Zhang R, Hu S, Zhang X, Yu W (2007) Dissolution kinetics of dolomite in water at elevated temperatures. Aquatic Geochemistry 13, 309–338.
| Dissolution kinetics of dolomite in water at elevated temperatures.Crossref | GoogleScholarGoogle Scholar |
