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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 77 Number 3 2024

CH23148Status of rare-earth perovskite catalysts in environmental applications

Pengyun Li, Aijun Gong 0000-0002-6261-1013, Jiandi Li, Lina Qiu, Xianghai Wang, Yue Chen, Jiayi Yin, Xinyu Huang and Yifan Chen

Chart showing synthesis methods, structures, modifiers and applications of rare-earth perovskite oxides

This paper reviews recent progress in rare-earth perovskite oxide materials, explores the effects of capacity factors, lattice defects, different metal active centers and perovskite modifications on crystal structure and applied properties, discusses the effects of synthesis processes (sol-gel, co-precipitation, microemulsion, hydrothermal, high-temperature) on their physical and chemical properties, and summarizes their applications in pollutant catalytic oxidation and photocatalytic degradation, VOCs gas sensing, and photocatalytic splitting of water for hydrogen production and carbon dioxide reduction and conversion. (Image credit: P. Li.)

CH23188Application of diglycolamide extractant in rare-earth extraction

Yiwen Wang, Aijun Gong 0000-0002-6261-1013, Lina Qiu, Yuzhen Bai, Yang Liu, Ge Gao and Weiyu Zhao

Spectra and molecular models for various analyses of the products of rare-earth extraction with diglycolamide

In the analytical methods for the extraction of rare-earth elements (REEs) by diglycolamide (DGA), liquid–liquid extraction experiments can demonstrate basic extraction properties, spectroscopic techniques can provide information on the inner-sphere coordination of REEIII–DGA complexes, and scattering techniques can be used to study the size and morphology of aggregates with nanoscale structures. (Image credits: bottom right, G. B. Deacon et al.; other images, A. Gong.)


Synthesis scheme showing the conversion of β-ketothioamides to various benzothiazole derivatives using iodine catalyst

We have developed a facile oxidative cyclization of β-ketothioamides for the simultaneous formation of a compound library similar to natural product benzothiazole derivatives, which are important structural motifs that are prevalent in both natural and designed compounds and display interesting biological and physical properties. (Image credit: M. Cui.)

CH23197Revisiting Staudinger and Ruzicka’s altered pyrethrolone: the cyclopentadienone dimers derived from pyrethrin I, cinerin I and jasmolin I

Oliver E. Hutt, Jamie A. Freemont, Stella Kyi, Stuart W. Littler, Ross P. McGeary, Peter J. Duggan 0000-0002-6056-5367, John Tsanaktsidis, Helen F. Cole, Maurice G. Kerr, Elizabeth H. Krenske 0000-0003-1911-0501 and John H. Ryan 0000-0003-2192-5099

Treatment of pyrethrin I, cinerin I or jasmolin I with NaOH forms cyclopentadienone dimers, isolated in 24–38% yields

On treatment with base, the natural pyrethrins pyrethrin I, cinerin I and jasmolin I undergo elimination to transient cyclopentadienones that dimerise to afford regioisomeric endo cycloadducts. (Image credit: J. H. Ryan.)

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