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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Mass Spectrometric Studies. XIV. Nitrochalcones

J Baldas and QN Porter

Australian Journal of Chemistry 32(10) 2249 - 2256
Published: 1979

Abstract

The mass spectra of chalcone, of its 2-, 2'-, 3-, 3'- and 4-nitro derivatives, and of a number of deuterated analogues, are described. Fragmentation of the 2-nitro isomer is very simple on account of anchimeric assistance to a carbon-carbon bond fission from the nitro group. The 2'-nitro isomer shows complex fragmentation resulting from oxygen transfer to the α,β-double bond. The 3-, 3'-, and 4-nitro compounds fragment in ways similar to that of chalcone itself, except for losses of hydroxy groups from their molecular ions. The origins of the transferred hydrogen atoms are shown by labelling experiments, and structures are suggested for the ions formed.

https://doi.org/10.1071/CH9792249

© CSIRO 1979

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