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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Synthesis and 13C N.M.R. Studies of Some Polycyclic Hydrocarbons with Trimethyltin at the Bridgehead

EW Della and HK Patney

Australian Journal of Chemistry 32(10) 2243 - 2248
Published: 1979

Abstract

The synthesis of (adamantan-1-yl)trimethylstannane (1), (bicyclo[2,2,2]oct-1-yl)trimethylstannane (2), (bicyclo[2,2,1]hept-1-yl)trimethylstannane (3), (cubanyl)trimethylstannane(4) and tricyco[[4,1,1,02,7]- hept-1-yl)trimethylstannane (5) is described and the carbon-13 nuclear magnetic resonance spectra of these compounds are reported. In particular, it is found that the coupling constant of the directly bonded tin bridgehead carbon atoms is not greatly dependent on the degree of s character of the carbon exocyclic bonding orbital and that vicinal coupling between tin and carbon is observed to fit a Karplus equation. A linear relationship occurs between 1J(117,119Sn,13CMe) and 2J(117,119Sn,13HMe).

https://doi.org/10.1071/CH9792243

© CSIRO 1979

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