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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Nickel-catalysed conjugate addition of trimethylaluminium to cyclopropyl ketones

L Bagnell, A Meisters and T Mole

Australian Journal of Chemistry 28(4) 821 - 824
Published: 1975

Abstract

Nickel-catalysed addition of trimethylaluminium to cyclopropyl ketones (RCOC3H5) affords 1-substituted pentan-1-ones (RCOC4H9; R = C6H4, 4- ClC6H4, 4-MeOC6H4, 3,4-Me2C6H3, c. 50% yield; R = 4-BrC6H4, 10%; and R = cyclopropyl, 30%).

https://doi.org/10.1071/CH9750821

© CSIRO 1975

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