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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The structure of monoclinic Tris(1,3-diphenyltriazenato)cobalt(III)-toluene(1/1) : An octahedral complex containing three four-membered chelate rings

M Corbett and BF Hoskins

Australian Journal of Chemistry 27(3) 665 - 670
Published: 1974

Abstract

Crystals of the toluene solvate of tris(l,3-diphenyltriazenato)cobalt(111) [abbreviated as Co(dpt)3], monoclinic with space group C2/c with a = 20.73(1), b = 16.30(3), c = 13.34(1) Å, β = 120.4(1)º containing four molecules per unit cell, are composed of discrete molecules of Co(dpt)3 and toluene, each separated from its neighbours by normal van der Waals distances. The six terminal nitrogen atoms of the three dpt groups bond to the cobalt atom, forming the three four-membered chelate rings.

https://doi.org/10.1071/CH9740665

© CSIRO 1974

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