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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Residue rotations of L-leucine in the Di-,Tri-,Tetra-, and Penta-peptides of L-leucine and Glycine containing one L-leucyl residue

AF Beechham

Australian Journal of Chemistry 20(9) 1983 - 1989
Published: 1967

Abstract

The molecular rotations, in aqueous solution, at 589 mμ, are tabulated for two hexapeptides and all the di-, tri-, tetra-, and penta-peptides of L-leucine and glycine containing one L-leucyl residue. The molecular rotations of the corresponding N-benzyloxycarbonyl peptides are also listed. It is shown that the ?residue rotation? of L-leucine varies widely, not only between those compounds in which the site of the residue is N-terminal, C-terminal, or internal, but also within these categories. Syntheses of certain of the compounds are described.

https://doi.org/10.1071/CH9671983

© CSIRO 1967

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