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RESEARCH ARTICLE
Contents Vol 73(11)

Fluorescence Enhancement Method for Enrofloxacin Extraction by Core–Shell Magnetic Microspheres

Linyan Yang A D , Leiming Fu A , Boxin Li A , Jifei Ma A , Cun Li A , Tianming Jin https://orcid.org/0000-0002-9760-1552 A D and Wen Gu B C D
+ Author Affiliations
- Author Affiliations

A Tianjin Key Laboratory of Agricultural Animal Breeding and Healthy Husbandry, College of Animal Science and Veterinary Medicine, Tianjin Agricultural University, Tianjin, 300384, China.

B College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin, 300071, China.

C Key Laboratory of Advanced Energy Materials Chemistry (KLAEMC), Nankai University, Tianjin, 300071, China.

D Corresponding authors. Email: y_linyan@163.com; JTMSCI@163.com; guwen68@nankai.edu.cn

Australian Journal of Chemistry 73(11) 1105-1111 https://doi.org/10.1071/CH19666
Submitted: 26 December 2019  Accepted: 31 March 2020   Published: 19 June 2020

Abstract

In this work, we present novel kinds of γ-Fe2O3@SiO2-NH2-CMC/MOF5 and γ-Fe2O3@SiO2-NH2-CMC/IRMOF3 magnetic metal–organic framework (MOF) nanoparticles which possess both magnetic characteristics and fluorescent properties. Here, [Zn4O(bdc)3] (MOF-5, bdc = 1,4-benzenedicarboxylate) is a kind of shell. IRMOF3, a known MOF with a cubic topology prepared from Zn(NO3)24H2O and 2-amino-1,4-benzene dicarboxylic acid, is another kind of shell which is attractive due to its highly porous, crystalline structure and the presence of non-coordinating amino groups on the benzenedicarboxylate (bdc) linker, which are amenable to post-synthetic modification. γ-Fe2O3@SiO2-NH2-CMC magnetic nanoparticles (MNPs) could be prepared by covalent modification of sodium carboxymethyl cellulose (CMC). The structure of γ-Fe2O3 nanoparticles could be determined by X-ray powder diffraction (XRD). X-ray photoelectron spectroscopy (XPS) spectra could be used for the characterisation of γ-Fe2O3@SiO2-NH2, γ-Fe2O3@SiO2-NH2-CMC, γ-Fe2O3@SiO2-NH2-CMC/MOF5, and γ-Fe2O3@SiO2-NH2-CMC/IRMOF3 nanoparticles. Magnetic solid-phase extraction (MSPE) of enrofloxacin (Enr) experiments exhibited that, for γ-Fe2O3@SiO2-NH2-CMC/IRMOF3, the best effects of adsorption could be obtained at pH 4 and 6, while elution conditions of 0.1 mol L−1 NaOH and 1 % sodium dodecyl sulfate could achieve the best elution effect. The addition of Tb3+ ions could sensitise the fluorescence of Enr. At the same time, via the addition of Tb3+ ions, coordination could occur between nanoparticles and Tb3+ ions, which could be verified by XPS.


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