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RESEARCH ARTICLE
Contents Vol 73(11)

Versatile Colorimetric Chemosensor Based on Bis(rhodamine) B Hydrazone for Rapid Detection of Multi-Analytes (Fe3+, Bi3+, Cu2+, and Hg2+) in Aqueous Media

Tamer El Malah https://orcid.org/0000-0002-2868-3857 A B and Hany F. Nour https://orcid.org/0000-0002-0261-1572 A B
+ Author Affiliations
- Author Affiliations

A Photochemistry Department, Chemical Industries Research Division, National Research Centre, 33 El Buhouth Street, PO Box 12622, Cairo, Egypt.

B Corresponding authors. Email: tmara_nrc3000@yahoo.com; hany.nour@daad-alumni.de

Australian Journal of Chemistry 73(11) 1112-1117 https://doi.org/10.1071/CH20046
Submitted: 12 February 2020  Accepted: 31 March 2020   Published: 22 June 2020

Abstract

A new bis(rhodamine) B hydrazone L, bearing two rhodamine chromophores, has been designed and synthesised in 70 % yield. The chemical structure of the new ligand L was characterised using different spectroscopic techniques. The receptor L was utilised for rapid ‘naked eye’ detection of Fe3+, Bi3+, Cu2+, and Hg2+ in THF–H2O (1 : 1, v/v) by displaying significant colour changes. The mechanism of detection of metal ions was based on the ring-opening of the spirolactam rings of L upon recognition. UV/Vis spectrometry was employed to investigate L–metal ion interactions in THF–H2O (1 : 1, v/v). The stoichiometries of the complexes were determined using Job’s method, which revealed 1 : 2 L–metal ion stoichiometries in the case of L–(Fe3+/Bi3+/Hg2+) complexes, while a 1 : 1 L–metal ion stoichiometry was recognised for the L–Cu2+ complex. 1H NMR spectroscopy was applied to study the L–metal ion interactions in DMSO-d6 and results are presented.


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