Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)
Gérard Audran A , Elena Bagryanskaya B C , Mariya Edeleva B C , Sylvain R. A. Marque A B D , Dmitriy Parkhomenko B , Evgeny Tretyakov B C and Svetlana Zhivetyeva B
+ Author Affiliations
- Author Affiliations
A Aix Marseille University, CNRS, ICR, UMR 7273, Case 551, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
B N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Lavrentjev Avenue, 9, Novosibirsk 630090, Russia.
C Novosibirsk State University, 2 Pirogova Street, Novosibirsk 630090, Russia.
D Corresponding author. Email: sylvain.marque@univ-amu.fr
Australian Journal of Chemistry 71(5) 334-340 https://doi.org/10.1071/CH17570
Submitted: 2 November 2017 Accepted: 28 January 2018 Published: 27 February 2018
Abstract
Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)2 (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90°C.
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