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RESEARCH ARTICLE
Contents Vol 70(7)

Luminescent Functionalised Supramolecular Coordination Polymers Based on an Aromatic Carboxylic Acid Ligand for Sensing Hg2+ Ions

Xiaojun Sun A C , Ping Yang A , Guangfeng Hou B , Jinzhi Wei A , Xueliang Wang A , Doudou Yang A , Xin Zhang A , Hong Dong A and Fengming Zhang A C
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, China.

B Engineering Research Center of Pesticide of Heilongjiang University, Heilongjiang University, Harbin 150080, China.

C Corresponding authors. Email: sunxiaojun@hrbust.edu.cn; zhangfm80@163.com

Australian Journal of Chemistry 70(7) 786-791 https://doi.org/10.1071/CH16600
Submitted: 24 October 2016  Accepted: 9 January 2017   Published: 13 February 2017

Abstract

Two luminescent functionalised supramolecular coordination polymers, namely, [Zn(TPDC-2CH3)(H2O)2]·H2O (1) and [Cd(TPDC-2CH3)(H2O)4]·H2O (2), were successfully synthesised by the reaction of 2′,5′-dimethyl-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid (H2TPDC-2CH3) with Zn2+ and Cd2+ ions, respectively. X-Ray crystallographic analysis reveals that both compounds 1 and 2 exhibit fascinating 3D supramolecular networks, in which metal ions are linked by ligands to form a 1D chain which further extends to a 3D structure through the interaction of hydrogen bonding. The use of 1 and 2 as luminescent sensors for the optical detection of metal ions: Na+, K+, Hg2+, Ag+, Ca2+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+, Mg2+, Al3+, Fe3+, Fe2+, In3+, Bi3+, and Cr3+ was carried out in aqueous solution, and the results indicated that compound 1 could effectively detect Hg2+ ions among various cations at room temperature, with a detection limit of 3.6 × 10−15 M.


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