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RESEARCH ARTICLE
Contents Vol 70(5)

Structural Systematics for Lanthanide(iii) Systems: Interactions of the Achiral Hexamminecobalt(iii) Cation with Tris(dipicolinato)lanthanate(iii) Anions*

Jack M. Harrowfield A B E , Irene Ling C , Brian W. Skelton A , Alexandre N. Sobolev A and Allan H. White A D
+ Author Affiliations
- Author Affiliations

A The University of Western Australia, School of Chemistry and Biochemistry, 35 Stirling Highway, Crawley, WA 6009, Australia.

B Current address: Institut de Science et d’Ingenierie Supramoléculaires, Université de Strasbourg, 8, allée Gaspard Monge, 67083 Strasbourg, France.

C School of Science, Monash University Malaysia, Jalan Lagoon Selatan, Bandar Sunway, 47500 Selangor, Malaysia.

D Deceased, March 2016.

E Corresponding author. Email: harrowfield@unistra.fr

Australian Journal of Chemistry 70(5) 485-493 https://doi.org/10.1071/CH16584
Submitted: 12 October 2016  Accepted: 1 November 2016   Published: 30 November 2016

Abstract

Extended structural studies, largely determinations at ~150 K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3] (Ln = La–Lu, and Y; dipic = dipicolinate = pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature of the interactions between the formally achiral cation and the chiral anions. They also provide a reference point for consideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.


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