Endocyclic and Endo–Exocyclic Silver(i) Complexes of Thiaoxaaza Macrocycles: Crystallographic and NMR Studies

Yunji Kang; Hyeong-Hwan Lee; Huiyeong Ju; Eunji Lee; Seulgi Kim; Joon-Hwa Lee; In-Hyeok Park; Shim Sung Lee

doi:10.1071/CH16467

RESEARCH ARTICLE

Endocyclic and Endo–Exocyclic Silver(i) Complexes of Thiaoxaaza Macrocycles: Crystallographic and NMR Studies

Yunji Kang ^A , Hyeong-Hwan Lee ^A , Huiyeong Ju ^A , Eunji Lee ^A , Seulgi Kim ^A , Joon-Hwa Lee ^A , In-Hyeok Park ^A ^B and Shim Sung Lee ^A ^B

+ Author Affiliations

- Author Affiliations

^A Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 52828, South Korea.

^B Corresponding authors. Email: pihghost@nate.com; sslee@gnu.ac.kr

Australian Journal of Chemistry 70(5) 456-460 https://doi.org/10.1071/CH16467
Submitted: 11 August 2016 Accepted: 19 August 2016 Published: 8 September 2016

Abstract

A comparative investigation of the coordination behaviour of a 19-membered NO₂S₂-macrocycle (L¹) and a 20-membered NO₂S₃-macrocycle (L²) is reported. On silver(i) complexation, L¹ yields a discrete endocyclic mononuclear complex, whereas L² affords a one-dimensional coordination polymer in which the endo-coordinated macrocyclic complex units are linked by silver(i) ions outside the cavity via endo–exo-coordination. The larger ring cavity along with the flexible nature of L² may induce the weaker endocyclic complexation and contribute to exocyclic coordination as well. In NMR titration studies for the corresponding complex system, however, no evidence of exocyclic coordination was observed. Instead, L¹ and L² form a stable endocyclic 1 : 1 silver(i) nitrate complex, with a higher affinity for the former ligand.

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Endocyclic and Endo–Exocyclic Silver(i) Complexes of Thiaoxaaza Macrocycles: Crystallographic and NMR Studies

Abstract

References

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