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RESEARCH ARTICLE
Contents Vol 69(9)

3D Ln–Organic Frameworks Featuring Lantern-Shaped Dihelicate Chains: Synthesis and Magnetic and Photophysical Properties

Shengyun Liao A , Peiyao Du B , Yanping Zhang B , Xin Fu B , Wen Gu B C D E and Xin Liu B C D E
+ Author Affiliations
- Author Affiliations

A Department of Applied Chemistry, Tianjin University of Technology, Tianjin 300384, China.

B Department of Chemistry, Nankai University, Tianjin 300071, China.

C Key Laboratory of Advanced Energy Material Chemistry, Tianjin 300071, China.

D Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China.

E Corresponding authors. Email: guwen68@nankai.edu.cn; liuxin64@nankai.edu.cn

Australian Journal of Chemistry 69(9) 1062-1069 https://doi.org/10.1071/CH16008
Submitted: 11 January 2016  Accepted: 18 March 2016   Published: 28 April 2016

Abstract

The in situ hydrothermal reaction of rare earth nitrate (Ln(NO3)3), 5-(4-carboxyl-1H-1,2,3-triazol-1-yl) isophthalic acid (H3ctia), and (NH4)2C2O4 resulted in the formation of a series of 3D 4f coordination polymers ([Ln(tia)(C2O4)0.5(H2O)]) (Ln = Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), and tia2– = 5-(1H-1,2,3-triazol-1-yl) isophthalate). The results of single crystal X-ray diffraction reveal that the dinuclear lantern sub-building units ([Ln2(CO2)4]2+) are linked by C2O42– to form dihelicate chains, which are connected by tia2– to afford a novel 3D metal–organic framework with an unordinary 3-nodal (2,3,8)-connected topological network with the Schläfli symbol of {4.62}2{42.616.89.10}{6}. Complexes 2, 3, 5, and 6 exhibit strong fluorescent emissions in the visible region and complexes 1, 2, and 6 show characteristic fluorescent emissions in the near-infrared region. In addition, the magnetic properties of complexes 4, 5, and 6 were also investigated.


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