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RESEARCH ARTICLE
Contents Vol 69(5)

Self-Assembly of Square-Planar Halide Complexes of Trimethylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Hexafluorophosphates*

J. Wolfram Wielandt A B , Simon Petrie A , Nathan L. Kilah A C , Anthony C. Willis A , Rian D. Dewhurst A D , Ferdinand Belaj B , Andreas Orthaber B , Robert Stranger A E and S. Bruce Wild A E
+ Author Affiliations
- Author Affiliations

A Research School of Chemistry, College of Physical and Mathematical Sciences, Australian National University, Canberra, ACT 2601, Australia.

B Institut für Chemie, Karl-Franzens-Universität Graz, 8010 Graz, Austria.

C School of Physical Sciences – Chemistry, University of Tasmania, Hobart, Tas. 7001, Australia.

D Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

E Corresponding authors. Email: rob.stranger@anu.edu.au; bruce.wild@anu.edu.au

Australian Journal of Chemistry 69(5) 524-532 https://doi.org/10.1071/CH15701
Submitted: 3 November 2015  Accepted: 26 December 2015   Published: 28 January 2016

Abstract

Square-planar halide complexes in which four trimethylphosphine-stabilized diphenyl-stibenium or -bismuthenium ions surround a central halide ion in discrete centrosymmetrical structures of C4h symmetry have been isolated and their structures determined by X-ray crystallography. The structures are stabilized by electrostatic interactions between the halide ion and four positively charged trimethylphosphine-stabilized diphenyl-stibenium or -bismuthenium ions, as well as four edge-to-face phenyl–phenyl embraces above and below the plane containing the nine main group elements. The parent halide-free trimethylphosphine-stabilized diphenyl-arsenium, -stibenium, and -bismuthenium hexaflurophosphate complexes have also been prepared and structurally characterized.


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