The Interaction between Remote Chiral Centres: A Pseudoracemic Example*,**
Paul V. Bernhardt A , Raymond M. Carman A B and Tri T. Le A
+ Author Affiliations
- Author Affiliations
A School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Qld 4072, Australia.
B Corresponding author. Email: carman@uq.edu.au
Australian Journal of Chemistry 68(4) 648-651 https://doi.org/10.1071/CH14597
Submitted: 30 September 2014 Accepted: 3 November 2014 Published: 5 January 2015
Abstract
High resolution 13C NMR, supported by X-ray crystallography, shows the true nature of the trichloro derivative from manool or sclareol as a mixture of diastereomers comprising 70 % 13R and 30 % 13S isomers.
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