A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU
Zhuo-Wei Wang A , Hui Zhao A , Min Chen A and Min Hu A B
+ Author Affiliations
- Author Affiliations
A Zhengzhou University of Light Industry, Zhengzhou, Henan 450002, China.
B Corresponding author. Email: humin@zzuli.edu.cn
Australian Journal of Chemistry 68(1) 161-164 https://doi.org/10.1071/CH14392
Submitted: 17 June 2014 Accepted: 30 July 2014 Published: 27 October 2014
Abstract
Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.
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