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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

A Highly Selective and Sensitive Chemosensor for Colorimetric and Fluorescent Detection of Al3+ and Living Cell Imaging

Xiao-Bo Li A , Jia-Yi Chen A and En-Ju Wang A B
+ Author Affiliations
- Author Affiliations

A School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China.

B Corresponding author. Email: enjuwang@163.com

Australian Journal of Chemistry 68(1) 156-160 https://doi.org/10.1071/CH14079
Submitted: 21 February 2014  Accepted: 26 April 2014   Published: 23 May 2014

Abstract

A colorimetric and fluorescent dual chemosensor for detecting Al3+, (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)nicotinohydrazide (HNN), was developed by combining 2-hydroxy-1-naphthaldehyde with nicotinohydrazide. Addition of Al3+ to EtOH–H2O solution of HNN gives rise to a visible colour change from colourless to light blue and a significantly enhanced fluorescence. Other metal ions including Na+, K+, Ca2+, Mg2+, Mn2+, Co2+, Ni2+, Cu2+, Cr3+, Ag+, Pb2+, Zn2+, Cd2+, Hg2+, Fe2+, and Fe3+ have no or little effect on the specific response of HNN to Al3+. The binding mode of HNN–Al3+ complex was further clarified by electrospray ionisation mass spectrometry and 1H NMR titration experiments.


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