Flexibility in the Self-Assembly of Silver Complexes: Coordination Polymers from Multi-Armed Pyridylmethyleneoxy Ligands
Peter J. Steel A and Christopher M. Fitchett A B
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, University of Canterbury, Christchurch 8140, New Zealand.
B Corresponding author. Email: chris.fitchett@canterbury.ac.nz
Australian Journal of Chemistry 66(4) 443-451 https://doi.org/10.1071/CH12464
Submitted: 10 October 2012 Accepted: 9 December 2012 Published: 22 January 2013
Abstract
The syntheses of new silver complexes of five isomeric bis(pyridylmethyleneoxy)benzenes, differing in the position of substitution on the benzene and pyridine rings, and three isomeric 1,3,5-tris(pyridylmethyleneoxy)benzenes, differing in the position of substitution on the pyridine ring, are described. The structures of six of these complexes were characterised using X-ray crystallography, showing the formation of coordination polymers for 3-pyridyl- and 4-pyridyl-armed ligands and discrete complexes for 2-pyridyl-armed ligands. The precise nature of the structure was further determined by the relative orientation of the pyridine rings in each case.
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