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RESEARCH ARTICLE
Contents Vol 66(1)

Aromatic Polycarboxylate-Tuned Assembly of Three New 2D Copper(ii) Complexes Derived from a Flexible Bis(pyridylamide) Ligand

Xiu-Li Wang A B , Fang-Fang Sui A , Hong-Yan Lin A , Jian Luan A and Guo-Cheng Liu A
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Bohai University, Liaoning Province Silicon Materials Engineering Technology Research Centre, Jinzhou 121000, P. R. China.

B Corresponding author. Email: wangxiuli@bhu.edu.cn

Australian Journal of Chemistry 66(1) 67-74 https://doi.org/10.1071/CH12357
Submitted: 28 July 2012  Accepted: 29 August 2012   Published: 19 September 2012

Abstract

Three new 2D copper(ii) complexes [Cu(NIPH)(L)] (1), [Cu(BDC)(L)(H2O)] (2), and [Cu(HBTC)(L)]·2H2O (3) were hydrothermally synthesized by self-assembly of aromatic polycarboxylates (H2NIPH = 5-nitroisophthalic acid, H2BDC = 1,3-benzenedicarboxylic acid, H3BTC = 1,3,5-benzenetricarboxylic acid) and the flexible bis(pyridylamide) ligand L (L = N,N′-di(3-pyridyl)succinamide), and structurally characterized by single crystal X-ray diffraction, and elemental, IR, and thermogravimetric analyses. Compound 1 is a 2D coordination polymer based on tri-flexural helix chains (left-, right-handed [Cu-L]n helix chains, and left-handed Cu-NIPH helix chain). Compound 2 exhibits a 2D wavelike polymeric layer structure constructed from a 1D [Cu-L]n sinusoidal chain and a 1D [Cu-BDC]n V-like chain. Compound 3 possesses a 2D double-layer network formed from 1D [Cu-L]n zigzag chains and 1D [Cu-HBTC]2n double chains. The fluorescent properties of the three compounds and the electrochemical behaviour of compound 2-bulk-modified carbon paste electrode were also studied.


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