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RESEARCH ARTICLE
Contents Vol 66(1)

Simple Method and Materials to Target Co(ii)-Dy(iii) Multi-Nuclear Magnetic Compounds and Single Molecule Magnets (SMMs): Synthesis, Structure, and Magnetic Studies

Yan Zhu A , Feng Luo A B , Xue-Feng Feng A , Zhen-Wei Liao A , Yu-Mei Song A , Hai-Xiao Huang A , Xiao-Zhao Tian A , Gong-Ming Sun A and Ming-Biao Luo A
+ Author Affiliations
- Author Affiliations

A College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou, 344000 Jiangxi, P. R. China.

B Corresponding author. Email: ecitluofeng@163.com

Australian Journal of Chemistry 66(1) 75-83 https://doi.org/10.1071/CH12336
Submitted: 18 July 2012  Accepted: 1 September 2012   Published: 4 October 2012

Abstract

In this work, based on mixed N-, O-donor ligands, a series of Co(ii)-Dy(iii) compounds are synthesised and characterised by single crystal X-ray diffraction and magnetic studies. These compounds include Co2(phen)2Dy(PhCOO)7 (1), Co2(phen)2Dy2(PhCOO)10 (2), Co(bpy)Dy(H2O)(CH3-PhCOO)5 (3), Co(phen)Dy(H2O)(CH3-PhCOO)5 (4), Co2(phen)2Dy(NO2-PhCOO)7 (5), Co2(phen)2Dy2(NO2-PhCOO)10 (6), and Co2(bpy)2Dy2(NO2-PhCOO)10 (7), where phen, bpy, CH3-PhCOOH, and NO2-PhCOOH are 1,10-phenanthroline, 2,2′-bipyridine, 3-methylbenzoic acid, and 3-nitrobenzoic acid, respectively. In these cases, di-, tri-, and tetranuclear Co-Dy clusters are observed. Direct current (DC) magnetic susceptibility reveals ferromagnetic or antiferromagnetic behaviour, whilst dynamic magnetic studies disclose single molecule magnet (SMM)-like slow magnetic relaxation for most of these compounds.


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