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RESEARCH ARTICLE
Contents Vol 65(4)

Synthesis of Cyclic Carbonate From Carbon Dioxide and Epoxide Using Amino Acid Ionic Liquid Under 1 atm Pressure

Qing Gong A , Huadong Luo A , Jin Cao A , Yuhan Shang A , Haibo Zhang A B , Wenjing Wang A and Xiaohai Zhou A B
+ Author Affiliations
- Author Affiliations

A College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, P. R. China.

B Corresponding author. Email: haibozhang1980@gmail.com (H. B. Zhang); zxh7954@hotmail.com (X. H. Zhou)

Australian Journal of Chemistry 65(4) 381-386 https://doi.org/10.1071/CH11462
Submitted: 6 December 2011  Accepted: 13 February 2012   Published: 20 March 2012

Abstract

Herein, we report an effective synthesis of cyclic carbonates by cycloaddition of carbon dioxide to epoxide using a modified amino acid ionic liquid as catalyst under 1 atm pressure. With triethylamine as co-catalyst, the catalytic activity of the l-proline based ionic liquid was greatly enhanced, and up to 97 % isolated yield of cyclic carbonate was achieved at 90°C under atmospheric pressure without organic solvent and metal component.


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