Constructive Embedding
Richard F. Langler A
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, Mount Allison University, Sackville, New Brunswick, E4L 1G8, Canada. Email: rlangler@mta.ca
Australian Journal of Chemistry 64(10) 1402-1408 https://doi.org/10.1071/CH11085
Submitted: 20 February 2011 Accepted: 14 June 2011 Published: 23 August 2011
Abstract
The application of perturbational expressions to the development of a novel set of approaches to embedding, i.e. constructive embedding, is presented. The most powerful of these approaches begins by exploiting the recently-recognized, free-electron-model-derived method for rapidly enumerating all possible embeddings for unbranched polyenes or polyenyls. Thereafter, one can employ constructive elaboration of new molecules which will have known embeddability.
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