Electroanalytical Determination of Some Sulfonamides on Overoxidized Polypyrrole Electrodes
Sabriye Percin Ozkorucuklu A D , Levent Ozcan B , Yucel Sahin C and Guleren Alsancak A
+ Author Affiliations
- Author Affiliations
A Suleyman Demirel University, Department of Chemistry, 32260, Isparta, Turkey.
B Afyon Kocatepe University, Department of Chemistry, 03200, Afyon, Turkey.
C Anadolu University, Department of Chemistry, 26470, Eskisehir, Turkey.
D Corresponding author. Email: percin@fef.sdu.edu.tr
Australian Journal of Chemistry 64(7) 965-972 https://doi.org/10.1071/CH10481
Submitted: 31 December 2010 Accepted: 22 March 2011 Published: 19 July 2011
Abstract
The electrochemical behaviours of five sulfonamides (sulfanilamide, sulfadiazine, sulfamerazine, sulfamonomethoxine, sulfamethoxazole) were investigated with overoxidized polypyrrole (OPPy) modified pencil graphite electrodes. The performance of the OPPy electrode was evaluated by differential pulse voltammetry in Britton–Robinson buffer solutions prepared in different ratio of acetonitrile-water binary mixture, between pH 1.5 and 7.0. The highest anodic signals of sulfonamides were obtained in Britton–Robinson buffer solution prepared in 50% (v/v) acetonitrile-water at pH 2.5 and 3.0. The OPPy electrodes exhibited good performance for sulfonamides with wide linear ranges (≈10–5–10–3 M), highly reproducible responses (RSD% ≤0.92) and correlation coefficients (≥0.9990). The calculated limits of detection were ~10–6 or 10–7 M at 3σ. In order to verify the reliability of the OPPy electrode as a sensor, it is used for determination of sulfamethoxazole in a pharmaceutical tablet. The recovery was found as 95.96% with the RSD% of 0.68. The overoxidized polypyrrole modified pencil graphite electrode showed a stable and reproducible response without any influence of interferent commonly existing in pharmaceutical containing sulfamethoxazole.
References
[1] A. Marzo, L. Dal Bo, J. Chromatogr. A 1998, 812, 17.| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1cXktFGlu70%3D&md5=11501e44113c856949657ab8dd9266a9CAS |
[2] S. Wang, H. Y. Zhang, L. Wang, Z. J. Duan, I. Kennedy, Food Addit. Contam. 2006, 23, 362.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28Xis1Citr0%3D&md5=c004d3c074b479b4ee007b972b3334e5CAS |
[3] K. Kishida, N. Furusawa, J. Chromatogr. A 2001, 937, 49.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXosFKlsLg%3D&md5=559d9a2aaa08cc1bb924fc9de03b70abCAS |
[4] C. Akay, S. A. Özkan, J. Pharm. Biomed. Anal. 2002, 30, 1207.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38Xot1CjsLw%3D&md5=e3beb50edc4fbb612c95e52a1eef9dabCAS |
[5] U. Koesukwiwat, S. Jayanta, N. Leepipatpiboon, J. Chromatogr. A 2007, 1140, 147.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXis1Cnsw%3D%3D&md5=3e49acc06f7f80bf8dea9cb0f7588830CAS |
[6] H. Amini, A. Ahmadiani, J. Pharm. Biomed. Anal. 2007, 43, 1146.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXht1OltLo%3D&md5=97864052f1ee772b89632ca41da79bbfCAS |
[7] T. You, X. Yang, E. Wang, Analyst 1998, 123, 2357.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1cXntFWhsrw%3D&md5=1842da64f2028c4e676849ee59230e30CAS |
[8] J. J. Berzas Nevado, G. Castaneda Penalvo, F. J. Guzman Bernardo, J. Chromatogr. A 2001, 918, 205.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXjtFCkur0%3D&md5=a30138163d136e15bf91eb9c256c2092CAS |
[9] B. Chiavarino, M. E. Crestoni, A. Di Marzio, S. Fornarini, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci. 1998, 706, 269.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1cXhtlOiu7Y%3D&md5=6638e7b4555783e3e968f8235a43e984CAS |
[10] V. B. Reeves, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci. 1999, 723, 127.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1MXhs1Ogtr0%3D&md5=c62655cd67aa8d365cc27450bd87f681CAS |
[11] N. Assassi, A. Tazerouti, J. P. Canselier, J. Chromatogr. A 2005, 1071, 71.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXivFyrtL0%3D&md5=91b605e5f00cd3cfa2342863050a705aCAS |
[12] J. M. Pingarron Carrazon, A. D. Recio, L. M. Polo Diez, Talanta 1992, 39, 631.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK38XksFKis78%3D&md5=eee2410bad3ffe3a07bd2045e4464f72CAS |
[13] M. Kotoucek, J. Skopalova, D. Michalkova, Anal. Chim. Acta 1997, 353, 61.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXmtlKnt78%3D&md5=3eda3898b21044d6c0be3fd9214968a3CAS |
[14] G. A. Evtyugin, G. K. Budnikov, J. Anal. Chem. 2002, 57, 750.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38Xls12lsL8%3D&md5=f7658fedef447ce674866c76abcaf9b8CAS |
[15] T. A. M. Msagati, J. C. Ngila, Talanta 2002, 58, 605.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XntVGku74%3D&md5=00a6794fa02b6892f4ad0c221542ac92CAS |
[16] C. D. Souza, O. C. Braga, I. C. Vieira, A. Spinelli, Sens. Actuators B 2008, 135, 66.
| Crossref | GoogleScholarGoogle Scholar |
[17] A. Ramanavicius, A. Ramanaviciene, A. Malinauskas, Electrochim. Acta 2006, 51, 6025.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28Xot1GltLo%3D&md5=8b4f512bc65555bfd69193ae9591b82dCAS |
[18] A. Özcan, Y. Şahin, M. Özsöz, S. Turan, Electroanalysis 2007, 19, 2208.
| Crossref | GoogleScholarGoogle Scholar |
[19] L. Özcan, Y. Şahin, Sens. Actuators B 2007, 127, 362.
| Crossref | GoogleScholarGoogle Scholar |
[20] C. Hsueh, A. Brajter-Toth, Anal. Chem. 1994, 66, 2458.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXkslaksL4%3D&md5=f7d020ea098a0c35ed8946986223b7ebCAS |
[21] J. Mostany, B. R. Scharifker, Synth. Met. 1997, 87, 179.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXjvFKntr4%3D&md5=fe69f342526fcf5faccd051ed283d805CAS |
[22] A. M. Farrington, J. M. Slater, Electroanalysis 1997, 9, 843.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXlt1agtL8%3D&md5=b2a6cf0b32cfbdce3f15f5cfcec1e04fCAS |
[23] Z. Gao, M. Zi, B. Chen, J. Electroanal. Chem. 1994, 373, 141.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXls1Grsb4%3D&md5=4bbc83029ea3bb1d01030fad1c8aeb97CAS |
[24] B. Deore, Z. Chen, T. Nagaoka, Anal. Chem. 2000, 72, 3989.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXltF2isbw%3D&md5=19fe0deddd88d26373228243e0eb3445CAS |
[25] T. Uğur, Ş. Yücel, E. Nusret, U. Yasemin, P. Kadir, Y. Attila, J. Electroanal. Chem. 2004, 570, 6.
| Crossref | GoogleScholarGoogle Scholar |
[26] M. R. Majidi, A. Jouyban, K. Asadpour-Zeynali, J. Electroanal. Chem. 2006, 589, 32.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XjtVKgs7g%3D&md5=882e2a85bbb6c4f037beb3cc50df2c16CAS |
[27] Y. Şahin, B. Ercan, M. Şahin, Talanta 2008, 75, 369.
| Crossref | GoogleScholarGoogle Scholar |
[28] M. Ishifune, R. Suzuki, Y. Mima, K. Uchida, N. Yamashita, S. Kashimura, Electrochim. Acta 2005, 51, 14.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXhtVams7bO&md5=d7ddbaa8b9bb5af41fc90eaa00442a24CAS |
[29] W. Gao, J. Song, N. Wu, J. Electroanal. Chem. 2005, 576, 1.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXhtVehsbc%3D&md5=afe96b8a1b105698ef3236d73b467f63CAS |
[30] M. Vestergaard, K. Kerman, E. Tamiya, Anal. Chim. Acta 2005, 538, 273.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXjs1SqsL8%3D&md5=14184f17dfdb7c527f7215c0a5cfc787CAS |
[31] P. Kara, A. Erdem, S. Girousi, M. Özsöz, J. Pharm. Biomed. Anal. 2005, 38, 191.
| 1:CAS:528:DC%2BD2MXks1Wnsbc%3D&md5=4804dff44a64a3c694e6af7001159ac9CAS |
[32] L. Özcan, M. Şahin, Y. Şahin, Sensors 2008, 8, 5792.
| Crossref | GoogleScholarGoogle Scholar |
[33] S. P. Özkorucuklu, Y. Şahin, G. Alsancak, Sensors 2008, 8, 8463.
| Crossref | GoogleScholarGoogle Scholar |
[34] L. Özcan, Y. Şahin, H. Türk, Biosens. Bioelectron. 2008, 24, 512.
| Crossref | GoogleScholarGoogle Scholar |
[35] J. Klimes, M. Mokry, Pharmazie 1997, 52, 448.
| 1:CAS:528:DyaK2sXktlehtL4%3D&md5=e77297567c24c193034fdbe8720f06f7CAS |
[36] T. N. Rao, B. V. Sarada, D. A. Tryk, A. Fujishim, J. Electroanal. Chem. 2000, 491, 175.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXovFWit7s%3D&md5=470c8ce01afeed51341bb1e6131c4f22CAS |
[37] A. Preechaworapun, S. Chuanuwatanakul, Y. Einaga, K. Grudpan, S. Motomizu, O. Chailapakul, Talanta 2006, 68, 1726.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XptVSitQ%3D%3D&md5=e5b044c07e8471859e65aa26e43e6e35CAS |
[38] J. Wang, M. Jiang, B. Mukherjee, Anal. Chem. 1999, 71, 4095.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1MXltVeit70%3D&md5=f2a06178b197833093eb7226d1d4e055CAS |
[39] J. Riber, C. Fuente, M. D. Vazquez, M. L. Tascon, P. S. Batanero, Talanta 2000, 52, 241.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXjs1CgsLg%3D&md5=d8b470907328beef7678c5a1f724865fCAS |
[40] A. Witkowski, M. S. Freund, A. Brajter-Toth, Anal. Chem. 1991, 63, 622.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK3MXhtFSmur0%3D&md5=d49b3d1915f8303bcc95a82d670fe437CAS |
[41] T.-F. Kang, G.-L. Shen, R.-Q. Yu, Talanta 1996, 43, 2007.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK28XmtVWjt7c%3D&md5=f73723f8c82609f95cb2c0dc120d8c0dCAS |
[42] A. Jaramillo, L. D. Spurlock, V. Young, A. Brajter-Toth, Analyst 1999, 124, 1215.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1MXkvFKitro%3D&md5=c57e83ec0c31703ab8512926ec77a211CAS |
[43] N. Şanlı, Ph. D. Thesis: Determination of some sulfonamides by liquid chromatographic technique 2007 (Suleyman Demirel University: Isparta, Turkey).
[44] J. R. Torres-Lapasio, M. C. Garcia-Alvarez-Coque, E. Bosch, M. Roses, J. Chromatogr. A 2005, 1089, 170.
| Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXmvFShtLg%3D&md5=7a321aad077909904942b7023b9317b9CAS |
