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RESEARCH ARTICLE
Contents Vol 64(2)

Novel Doped Tungstovanadate and Molybdovanadate with Bi-antimony-Capped Keggin Structure

Zhangang Han A B , Jingjing Wu A , Yuanzhe Gao A and Xueliang Zhai A
+ Author Affiliations
- Author Affiliations

A College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, Hebei, 050016, China.

B Corresponding author. Email: hanzg116@yahoo.com.cn

Australian Journal of Chemistry 64(2) 197-205 https://doi.org/10.1071/CH10220
Submitted: 30 May 2010  Accepted: 23 November 2010   Published: 15 February 2011

Abstract

Three novel V-centred Keggin-based compounds containing cap-shaped Sb atoms: (HDMF)2[(VO4)W5.65V7.74Sb2.61O36.77]·6H2O (1), [Co(phen)3]2[(VO4)Mo9.58V2.42Sb2O36]·6H2O (2) and [Ni(phen)2(H2O)]2[(VO4)Mo8V4Sb2O36]·2H2O (3) (DMF = dimethylformamide; phen = 1,10-phenanthroline) have been synthesized and characterized. X-ray diffraction analysis revealed that compound 1 consists of an unusually one-dimensional 12-tungstovanadate Keggin-based polymer, in which the reduced tungstovanadate Keggin species are stabilized by introducing capping {VO} and {Sb} groups and then linked into chains via V(Sb)–O–V(Sb) interactions. Both 2 and 3 are built from secondary metal–ligand groups (Co-phen for 2, Ni-phen for 3) and 12-molybdovanadate doped Keggin-type cores with two antimony atoms capping two opposite sites. The anion in 3 represents a bi-capped and bi-supported Keggin-type structure. The electrochemical properties of 2- and 3-modified carbon paste electrodes (2-CPE and 3-CPE) are also studied.


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