Heteropolymetallic Supramolecular Solid-State Architectures Constructed from Dicyanoaurate Ion, Phen, and 3d Metals
Gong-Feng Xu A , Zhan-Quan Liu A B , Hui-Bo Zhou A , Yang Guo A and Dai-Zheng Liao AA Department of Chemistry, Nankai University, Tianjin 300071, China.
B Corresponding author. Email: coord@nankai.edu.cn
Australian Journal of Chemistry 59(9) 640-646 https://doi.org/10.1071/CH05247
Submitted: 7 September 2005 Accepted: 13 September 2006 Published: 19 October 2006
Abstract
Two new supramolecular polymeric coordination complexes, {Zn(phen)2[Au2(CN)4](H2O)}·1.5H2O 1 and {Mn(phen)[Au2(CN)4](H2O)}·PriOH 2, have been obtained through a self-assembly process. The three-dimensional supramolecular architectures of compounds 1 and 2 are sustained by aurophilic, hydrogen-bonding, and/or π–π interactions. Gold atoms linked with aurophilic bonds arrange in a pattern not frequently observed.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (no. 20071019, 90501002, 20331010), the Natural Science Foundation of Tianjin (no. 043602211), and the Natural Science Key Foundation of Tianjin.
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