Review and outlook for agromineral research in agriculture and climate mitigation
Guanru Zhang A , Jinting Kang B C , Tianxing Wang D and Chen Zhu B EA School of Earth Sciences, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China.
B Department of Earth and Atmospheric Sciences, Indiana University, Bloomington, IN 47405, USA.
C CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China.
D Jiaxing Vocational Technical College, 547 Tongxiang Avenue, Jiaxing 314036, China.
E Corresponding author. Email: chenzhu@indiana.edu
Soil Research 56(2) 113-122 https://doi.org/10.1071/SR17157
Submitted: 12 June 2017 Accepted: 18 August 2017 Published: 2 November 2017
Abstract
Agrominerals are finely ground rocks and minerals used as low-cost fertilisers, and they have received more attention in recent years as sustainable development and climate change mitigation have come to the forefront of societal concerns. Here, we summarise progress in agromineral research over the last 20 years, and discuss the challenges and opportunities of this discipline. The idea of agrominerals has been around since the early 19th century. However, widespread application is subject to economic practicality. In recent years, two big trends have dominated agromineral research. First, some global warming mitigation strategies, such as ‘enhanced chemical weathering’ and bio-energy carbon capture and storage call for the application of rock powders in arable land on a massive scale. This gives agromineral research an urgency and significance. Second, advances in knowledge of mineral weathering kinetics are poised to transform predictions of agronomic effectiveness from mere empirical studies to more quantitative evaluation. We now have a much better understanding of the factors that influence weathering and nutrient release rates. We forecast that rapid advances in some areas of biogeochemistry will enable advances in the study of agrominerals. In particular, we will be able to measure weathering and nutrient release rates at the field scale, and ultimately to predict kinetic processes of mineral dissolution or precipitation in soil–water–plant systems and the cycling of nutrients and toxic elements in agricultural land.
Additional keywords: agrogeology, agromineral, climate mitigation, enhanced weathering, kinetics.
References
Abdel-Rahman AFM (2001) Peraluminous plutonism: nature and origin of the Moly May leucogranite and its Coast Plutonic Complex granitic host-rocks, northwestern British Columbia. Canadian Mineralogist 39, 1181–1196.| Peraluminous plutonism: nature and origin of the Moly May leucogranite and its Coast Plutonic Complex granitic host-rocks, northwestern British Columbia.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXotFajtbs%3D&md5=06e3fbe55a74d25467191e5563c20bf6CAS |
Abou-el-Seoud II, Abdel-Megeed A (2012) Impact of rock materials and biofertilizations on P and K availability for maize (Zea Maize) under calcareous soil conditions. Saudi Journal of Biological Sciences 19, 55–63.
| Impact of rock materials and biofertilizations on P and K availability for maize (Zea Maize) under calcareous soil conditions.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38Xnsleltw%3D%3D&md5=1681043eb927e2ec535fc663b7f1d261CAS |
Aksoy A, Ahmed M, Matter WSA (2002) Gamma-ray spectroscopic and PIXE analysis of selected samples from the phosphorite deposits of Northwestern Saudi Arabia. Journal of Radioanalytical and Nuclear Chemistry 253, 517–521.
| Gamma-ray spectroscopic and PIXE analysis of selected samples from the phosphorite deposits of Northwestern Saudi Arabia.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XnsFOksrg%3D&md5=d019cf9777136389d6e878863f4fef2cCAS |
Akter M, Akagi T (2005) Effect of fine root contact on plant-induced weathering of basalt. Soil Science and Plant Nutrition 51, 861–871.
| Effect of fine root contact on plant-induced weathering of basalt.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XhvFChsA%3D%3D&md5=eab2650f0d9cb91cb88d28089973bbc1CAS |
Akter M, Akagi T (2010) Dependence of plant-induced weathering of basalt and andesite on nutrient conditions. Geochemical Journal 44, 137–150.
| Dependence of plant-induced weathering of basalt and andesite on nutrient conditions.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXhtVWlsrfN&md5=7a2ab51f50f64606feecdc1e1846ba65CAS |
Alekseyev VA, Medvedeva LS, Prisyagina NI, Meshalkin SS, Balabin AI (1997) Change in the dissolution rates of alkali feldspars as a result of secondary mineral precipitation and approach to equilibrium. Geochimica et Cosmochimica Acta 61, 1125–1142.
| Change in the dissolution rates of alkali feldspars as a result of secondary mineral precipitation and approach to equilibrium.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXhvFygs70%3D&md5=46a5780a8dd3e352c4a3c1a435ee8a39CAS |
Anbeek C (1993) The effect of natural weathering on dissolution rates. Geochimica et Cosmochimica Acta 57, 4963–4975.
| The effect of natural weathering on dissolution rates.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXhtFWqsr8%3D&md5=69c493ec6f8e9f7738e308d448077975CAS |
Arcand MM, Schneider KD (2006) Plant-and microbial-based mechanisms to improve the agronomic effectiveness of phosphate rock: a review. Anais da Academia Brasileira de Ciencias 78, 791–807.
| Plant-and microbial-based mechanisms to improve the agronomic effectiveness of phosphate rock: a review.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXkslWjtrY%3D&md5=336fbf2d40a9b1276c54860a848f5d60CAS |
Baláž P, Turianicová E, Fabián M, Kleiv RA, Briančin J, Obut A (2008) Structural changes in olivine (Mg, Fe)2SiO4 mechanically activated in high-energy mills. International Journal of Mineral Processing 88, 1–6.
| Structural changes in olivine (Mg, Fe)2SiO4 mechanically activated in high-energy mills.Crossref | GoogleScholarGoogle Scholar |
Barea J, Toro M, Orozco M, Campos E, Azcón R (2002) The application of isotopic (32 P and 15 N) dilution techniques to evaluate the interactive effect of phosphate-solubilizing rhizobacteria, mycorrhizal fungi and Rhizobium to improve the agronomic efficiency of rock phosphate for legume crops. Nutrient Cycling in Agroecosystems 63, 35–42.
| The application of isotopic (32 P and 15 N) dilution techniques to evaluate the interactive effect of phosphate-solubilizing rhizobacteria, mycorrhizal fungi and Rhizobium to improve the agronomic efficiency of rock phosphate for legume crops.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XnsFyls74%3D&md5=29202d5703e0670fcf7436b7878fe2a2CAS |
Berner RA, Berner EK (1997) Silicate weathering and climate. In ‘Tectonic uplift and climate change’. (Ed. WF Ruddiman) pp. 353–364. (Springer US: New York)
Blouin M, Hodson ME, Delgado EA, Baker G, Brussaard L, Butt KR, Dai J, Dendooven L, Peres G, Tondoh JE (2013) A review of earthworm impact on soil function and ecosystem services. European Journal of Soil Science 64, 161–182.
| A review of earthworm impact on soil function and ecosystem services.Crossref | GoogleScholarGoogle Scholar |
Blum AE, Stillings LL (1995) Feldspar dissolution kinetics. In ‘Chemical weathering rates of silicate minerals’. (Eds AF White, SL Brantley) pp. 291–346. (Mineralogical Society of America: Washington, D.C.)
Brantley SL (2008) Kinetics of Mineral Dissolution. In ‘Kinetics of water-rock interaction’. (Eds SL Brantley, JD Kubicki, AF White) pp. 151–210. (Springer New York: New York, NY)
Bunker B (1994) Molecular mechanisms for corrosion of silica and silicate glasses. Journal of Non-Crystalline Solids 179, 300–308.
| Molecular mechanisms for corrosion of silica and silicate glasses.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2MXitlanurY%3D&md5=135e42e0312201eabbc68d1bbe531f49CAS |
Carpenter D, Hodson ME, Eggleton P, Kirk C (2007) Earthworm induced mineral weathering: Preliminary results. European Journal of Soil Biology 43, S176–S183.
| Earthworm induced mineral weathering: Preliminary results.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXhtlGjsL7E&md5=9c94ac152c68fab660467298f365f7b6CAS |
Casey WH, Bunker BC (1990) The leaching of mineral and glass surfaces during dissolution. In ‘Mineral-water interface geochemistry’. (Eds M Hochella, A White) pp. 397–426. (Mineralogical Society of America: Washington, D.C.)
Casey WH, Ludwig C (1995) Silicate mineral dissolution as a ligand-exchange reaction. Reviews in Mineralogy and Geochemistry 31, 87–117.
Casey WH, Westrich HR, Arnold GW (1988) Surface chemistry of labradorite feldspar reacted with aqueous solutions at pH = 2, 3, and 12. Geochimica et Cosmochimica Acta 52, 2795–2807.
| Surface chemistry of labradorite feldspar reacted with aqueous solutions at pH = 2, 3, and 12.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL1MXhtFynsbs%3D&md5=73fcb819172b61618525a0103efaad89CAS |
Casey WH, Banfield JF, Westrich HR, McLaughlin L (1993) What do dissolution experiments tell us about natural weathering? Chemical Geology 105, 1–15.
| What do dissolution experiments tell us about natural weathering?Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK3sXisFyiurk%3D&md5=4a49bef51c9a2577b2cb2fb6facb7813CAS |
Chien S (1993) Solubility assessment for fertilizer containing phosphate rock. Fertilizer Research 35, 93–99.
| Solubility assessment for fertilizer containing phosphate rock.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXhs1amsrs%3D&md5=df900f10329e45cd6ad84d3437f855c1CAS |
Chien S, Menon R (1995a) Agronomic evaluation of modified phosphate rock products. Fertilizer Research 41, 197–209.
| Agronomic evaluation of modified phosphate rock products.Crossref | GoogleScholarGoogle Scholar |
Chien S, Menon R (1995b) Factors affecting the agronomic effectiveness of phosphate rock for direct application. Fertilizer Research 41, 227–234.
| Factors affecting the agronomic effectiveness of phosphate rock for direct application.Crossref | GoogleScholarGoogle Scholar |
Chou L, Wollast R (1985) Steady-state kinetics and dissolution mechanisms of albite. American Journal of Science 285, 963–993.
| Steady-state kinetics and dissolution mechanisms of albite.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL28XltlOlug%3D%3D&md5=3e1e0d4675e6db5e9ca1f289fa5ca16fCAS |
Ciceri D, de Oliveira M, Stokes RM, Skorina T, Allanore A (2017) Characterization of potassium agrominerals: Correlations between petrographic features, comminution and leaching of ultrapotassic syenites. Minerals Engineering 102, 42–57.
| Characterization of potassium agrominerals: Correlations between petrographic features, comminution and leaching of ultrapotassic syenites.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC28XitFentb3O&md5=31b163a9663f76d0d782097331007c9cCAS |
da Conceição FT, Bonotto DM (2006) Radionuclides, heavy metals and fluorine incidence at Tapira phosphate rocks, Brazil, and their industrial (by) products. Environmental Pollution 139, 232–243.
| Radionuclides, heavy metals and fluorine incidence at Tapira phosphate rocks, Brazil, and their industrial (by) products.Crossref | GoogleScholarGoogle Scholar |
Dakora FD, Phillips DA (2002) Root exudates as mediators of mineral acquisition in low-nutrient environments. Plant and Soil 245, 35–47.
| Root exudates as mediators of mineral acquisition in low-nutrient environments.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XnvVCit70%3D&md5=44e4dc3e596171cac075fe91f1d884c0CAS |
Fuss S, Canadell JG, Peters GP, Tavoni M, Andrew RM, Ciais P, Jackson RB, Jones CD, Kraxner F, Nakicenovic N (2014) Betting on negative emissions. Nature Climate Change 4, 850–853.
| Betting on negative emissions.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXhsFyhsrjN&md5=34c7e702294d8576e0da164f9d8088f8CAS |
Ganor J, Lu P, Zheng Z, Zhu C (2007) Bridging the gap between laboratory measurements and field estimations of weathering using simple calculations. Environmental Geology 53, 599–610.
| Bridging the gap between laboratory measurements and field estimations of weathering using simple calculations.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXht1amu77E&md5=28dc79d30d25cbc47898f84bc67e575fCAS |
Ganor J, Reznik IJ, Rosenberg YO (2009) Organics in water-rock interactions. Reviews in Mineralogy and Geochemistry 70, 259–369.
| Organics in water-rock interactions.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXnvFGrsr8%3D&md5=882b2d62bb555cf1a11d740c92443e6fCAS |
Ghani A, Rajan S, Lee A (1994) Enhancement of phosphate rock solubility through biological processes. Soil Biology & Biochemistry 26, 127–136.
| Enhancement of phosphate rock solubility through biological processes.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXhs1alsrc%3D&md5=086906cc64ae66e784ca40f98e547d8eCAS |
Gillman G (1980) The effect of crushed basalt scoria on the cation exchange properties of a highly weathered soil. Soil Science Society of America Journal 44, 465–468.
| The effect of crushed basalt scoria on the cation exchange properties of a highly weathered soil.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL3cXkvFCisrw%3D&md5=535d02263e1f04f7839c2c3ce1273dafCAS |
Gillman G, Burkett D, Coventry R (2001) A laboratory study of application of basalt dust to highly weathered soils: Effect on soil cation chemistry. Soil Research 39, 799–811.
| A laboratory study of application of basalt dust to highly weathered soils: Effect on soil cation chemistry.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXmtVKjsr0%3D&md5=68a4e37fb88a415eec9214d8fb12c2edCAS |
Gillman G, Burkett D, Coventry R (2002) Amending highly weathered soils with finely ground basalt rock. Applied Geochemistry 17, 987–1001.
| Amending highly weathered soils with finely ground basalt rock.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XktlKgtLw%3D&md5=6c38885e28cbd2f41fee400e104f2ba5CAS |
Goddéris Y, Brantley SL, François LM, Schott J (2013) Rates of consumption of atmospheric CO2 through the weathering of loess during the next 100 yr of climate change. Biogeosciences 10, 135–148.
| Rates of consumption of atmospheric CO2 through the weathering of loess during the next 100 yr of climate change.Crossref | GoogleScholarGoogle Scholar |
Gruber C, Harpaz L, Zhu C, Bullen TD, Ganor J (2013) A new approach for measuring dissolution rates of silicate minerals by using silicon isotopes. Geochimica et Cosmochimica Acta 104, 261–280.
| A new approach for measuring dissolution rates of silicate minerals by using silicon isotopes.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXitVOntLc%3D&md5=165b571405f79bff0d9516c9d3b59a03CAS |
Guidry MW, Mackenzie FT (2000) Apatite weathering and the Phanerozoic phosphorus cycle. Geology 28, 631–634.
| Apatite weathering and the Phanerozoic phosphorus cycle.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXltVyjs70%3D&md5=153a0f909aa6dbe36799bd9bbd2b1e0eCAS |
Guidry MW, Mackenzie FT (2003) Experimental study of igneous and sedimentary apatite dissolution: Control of pH, distance from equilibrium, and temperature on dissolution rates. Geochimica et Cosmochimica Acta 67, 2949–2963.
| Experimental study of igneous and sedimentary apatite dissolution: Control of pH, distance from equilibrium, and temperature on dissolution rates.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXlvFaqurw%3D&md5=4f031c7c895272121f9c45b42f322462CAS |
Harley A, Gilkes R (2000) Factors influencing the release of plant nutrient elements from silicate rock powders: a geochemical overview. Nutrient Cycling in Agroecosystems 56, 11–36.
| Factors influencing the release of plant nutrient elements from silicate rock powders: a geochemical overview.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3cXhvFWmtb4%3D&md5=5961f879db7cf87b6d2bbe5621dad35dCAS |
Hartmann J, West AJ, Renforth P, Köhler P, De La Rocha CL, Wolf‐Gladrow DA, Dürr HH, Scheffran J (2013) Enhanced chemical weathering as a geoengineering strategy to reduce atmospheric carbon dioxide, supply nutrients, and mitigate ocean acidification. Reviews of Geophysics 51, 113–149.
| Enhanced chemical weathering as a geoengineering strategy to reduce atmospheric carbon dioxide, supply nutrients, and mitigate ocean acidification.Crossref | GoogleScholarGoogle Scholar |
Haug TA, Kleiv RA, Munz IA (2010) Investigating dissolution of mechanically activated olivine for carbonation purposes. Applied Geochemistry 25, 1547–1563.
| Investigating dissolution of mechanically activated olivine for carbonation purposes.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXht1Wjtb%2FF&md5=f574e748664e63107cdf45e73b2ab30dCAS |
Hellmann R, Eggleston CM, Hochella MF, Crerar DA (1990) The formation of leached layers on albite surfaces during dissolution under hydrothermal conditions. Geochimica et Cosmochimica Acta 54, 1267–1281.
| The formation of leached layers on albite surfaces during dissolution under hydrothermal conditions.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK3cXkvVahtrw%3D&md5=26c7ffb72082ebd28b25df8a5f45b483CAS |
Hellmann R, Penisson JM, Hervig RL, Thomassin JH, Abrioux MF (2003) An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation. Physics and Chemistry of Minerals 30, 192–197.
| An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXjsFejsbc%3D&md5=c27c62c542d5fae1195e4f969c13d9beCAS |
Hinsinger P (2001) Bioavailability of inorganic P in the rhizosphere as affected by root-induced chemical changes: a review. Plant and Soil 237, 173–195.
| Bioavailability of inorganic P in the rhizosphere as affected by root-induced chemical changes: a review.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XovVWlsQ%3D%3D&md5=f06bd3d2a581092c6615f9cefd32c535CAS |
Hinsinger P, Gilkes R (1995) Root-induced dissolution of phosphate rock in the rhizosphere of lupins grown in alkaline soil. Australian Journal of Soil Research 33, 477–489.
| Root-induced dissolution of phosphate rock in the rhizosphere of lupins grown in alkaline soil.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2MXmslOrtb4%3D&md5=cd922ebf84e56cbd373225a9da8d3e69CAS |
Hinsinger P, Gilkes RJ (1997) Dissolution of phosphate rock in the rhizosphere of five plant species grown in an acid, P-fixing mineral substrate. Geoderma 75, 231–249.
| Dissolution of phosphate rock in the rhizosphere of five plant species grown in an acid, P-fixing mineral substrate.Crossref | GoogleScholarGoogle Scholar |
Hinsinger P, Jaillard B (1993) Root-induced release of interlayer potassium and vermiculitization of phlogopite as related to potassium depletion in the rhizosphere of ryegrass. European Journal of Soil Science 44, 525–534.
| Root-induced release of interlayer potassium and vermiculitization of phlogopite as related to potassium depletion in the rhizosphere of ryegrass.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXhs1alsLo%3D&md5=84a3097bc5086f5257ba84b7140308deCAS |
Hinsinger P, Bolland M, Gilkes R (1995) Silicate rock powder: effect on selected chemical properties of a range of soils from Western Australia and on plant growth as assessed in a glasshouse experiment. Fertilizer Research 45, 69–79.
| Silicate rock powder: effect on selected chemical properties of a range of soils from Western Australia and on plant growth as assessed in a glasshouse experiment.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK28XltFOntrk%3D&md5=c9b8c7e6111e7881d748167de4c1b532CAS |
Hinsinger P, Barros ONF, Benedetti MF, Noack Y, Callot G (2001) Plant-induced weathering of a basaltic rock: experimental evidence. Geochimica et Cosmochimica Acta 65, 137–152.
| Plant-induced weathering of a basaltic rock: experimental evidence.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXitVygtQ%3D%3D&md5=5da7b2f0a6d8fc6e50e9c26d298c4a97CAS |
Hodson ME, Black S, Brinza L, Carpenter D, Lambkin DC, Mosselmans JFW, Palumbo-Roe B, Schofield PF, Sizmur T, Versteegh EAA (2014) Biology as an agent of chemical and mineralogical change in soil. Procedia Earth and Planetary Science 10, 114–117.
| Biology as an agent of chemical and mineralogical change in soil.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXhsFOru7bN&md5=9788fe0a36a339b02d94895b443778e8CAS |
Holdren GR, Speyer PM (1985) pH dependence changes in the rats and stoichiometry of dissolution of an alkali feldspar at room temperature. American Journal of Science 285, 994–1026.
| pH dependence changes in the rats and stoichiometry of dissolution of an alkali feldspar at room temperature.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL28XltlOluw%3D%3D&md5=5ea1b763081338752ee4deb0d5b923abCAS |
IPCC (2007) ‘Climate change 2007: the physical science basis.’ (Cambridge University Press: Cambridge, UK and New York, NY, USA)
IPCC (2014) Carbon dioxide: projected emissions and concentrations. Available at http://www.ipcc-data.org/observ/ddc_co2.html
Kanabo IAK, Gilkes RJ (1987) The role of soil pH in the dissolution of phosphate rock fertilizers. Nutrient Cycling in Agroecosystems 12, 165–173.
Kleiv RA, Thornhill M (2007) Production of mechanically activated rock flour fertilizer by high intensive ultrafine grinding. Minerals Engineering 20, 334–341.
| Production of mechanically activated rock flour fertilizer by high intensive ultrafine grinding.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXjtFGmurk%3D&md5=90bd28da79ea361f1384da8ec6c3bfe4CAS |
Köhler P, Hartmann J, Wolfgladrow DA (2010) Geoengineering potential of artificially enhanced silicate weathering of olivine. Proceedings of the National Academy of Sciences of the United States of America 107, 20228–20233.
| Geoengineering potential of artificially enhanced silicate weathering of olivine.Crossref | GoogleScholarGoogle Scholar |
Kongshaug G, Bockman OC, Kaarstad O, Morka H (1992) Inputs of trace elements to soils and plants. In ‘Chemical climatology and geomedical problems’. (Eds J Låg) pp. 185–216. (Norsk Hydro: Oslo, Norway)
Kratz S, Schnug E (2006) Rock phosphates and P fertilizers as sources of U contamination in agricultural soils. In ‘Uranium in the environment’. (Eds BJ Merkel, A Hasche-Berger) pp. 57–67. (Springer: Netherlands)
Lasaga AC, Soler JM, Ganor J, Burch TE, Nagy KL (1994) Chemical weathering rate laws and global geochemical cycles. Geochimica et Cosmochimica Acta 58, 2361–2386.
| Chemical weathering rate laws and global geochemical cycles.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2cXktl2ntLc%3D&md5=80a1b4cf938ca3f6f7a9ed9cdb356c2eCAS |
Léon L, Fenster W, Hammond L (1986) Agronomic potential of eleven phosphate rocks from Brazil, Colombia, Peru, and Venezuela. Soil Science Society of America Journal 50, 798–802.
| Agronomic potential of eleven phosphate rocks from Brazil, Colombia, Peru, and Venezuela.Crossref | GoogleScholarGoogle Scholar |
Leonardos OH, Theodoro SH, Assad ML (2000) Remineralization for sustainable agriculture: a tropical perspective from a Brazilian viewpoint. Nutrient Cycling in Agroecosystems 56, 3–9.
| Remineralization for sustainable agriculture: a tropical perspective from a Brazilian viewpoint.Crossref | GoogleScholarGoogle Scholar |
Lim H, Gilkes R, McCormick P (2003) Beneficiation of rock phosphate fertilisers by mechano-milling. Nutrient Cycling in Agroecosystems 67, 177–186.
| Beneficiation of rock phosphate fertilisers by mechano-milling.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXmvVOmtbk%3D&md5=087a87e22fd513271b044a3b614e062cCAS |
Lucas Y (2001) The role of plants in controlling rates and products of weathering: importance of biological pumping. Annual Review of Earth and Planetary Sciences 12, 313–316.
Manning DAC (2008) Phosphate minerals, environmental pollution and sustainable agriculture. Elements 4, 105–108.
| Phosphate minerals, environmental pollution and sustainable agriculture.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXmvV2rtL8%3D&md5=580fc989d1340f5b828c11fe16fe2cf1CAS |
Manning DA (2010) Mineral sources of potassium for plant nutrition. A review. Agronomy for Sustainable Development 30, 281–294.
| Mineral sources of potassium for plant nutrition. A review.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXntlOmtb8%3D&md5=c1e7237b92353a9471e248c3eb2b1acdCAS |
Manning DAC (2015) How will minerals feed the world in 2050? Proceedings of the Geologists’ Association 126, 14–17.
Manning DA (2017) Innovation in resourcing geological materials as crop nutrients. Natural Resources Research
| Innovation in resourcing geological materials as crop nutrients.Crossref | GoogleScholarGoogle Scholar |
Manning DAC, Renforth P, Lopez-Capel E, Robertson S, Ghazireh N (2013) Carbonate precipitation in artificial soils produced from basaltic quarry fines and composts: An opportunity for passive carbon sequestration. International Journal of Greenhouse Gas Control 17, 309–317.
| Carbonate precipitation in artificial soils produced from basaltic quarry fines and composts: An opportunity for passive carbon sequestration.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXht1ylsLbL&md5=bce1c9ee8ec558179dd35b9ff742a00dCAS |
Manning DAC, Baptista J, Sanchez Limon M, Brandt K (2017) Testing the ability of plants to access potassium from framework silicate minerals. The Science of the Total Environment 574, 476–481.
| Testing the ability of plants to access potassium from framework silicate minerals.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC28XhsFCmt7vE&md5=337dbc375fc7ea223b5c77009748a01cCAS |
Marini L (2006) ‘Geological sequestration of carbon dioxide: thermodynamics, kinetics, and reaction path modeling.’ (Elsevier: The Netherlands)
Marty NCM, Claret F, Lassin A, Tremosa J, Blanc P, Madé B, Giffaut E, Cochepin B, Tournassat C (2015) A database of dissolution and precipitation rates for clay-rocks minerals. Applied Geochemistry 55, 108–118.
| A database of dissolution and precipitation rates for clay-rocks minerals.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXhvVWksr%2FJ&md5=8d9135af2dc41e3415dd7e7e51fc04f0CAS |
Mclaughlin MJ (1996) Review: the behaviour and environmental impact of contaminants in fertilizers. Australian Journal of Soil Research 34, 3091–3102.
Mohammed S, Brandt K, Gray N, White M, Manning D (2014) Comparison of silicate minerals as sources of potassium for plant nutrition in sandy soil. European Journal of Soil Science 65, 653–662.
| Comparison of silicate minerals as sources of potassium for plant nutrition in sandy soil.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXhsFGhsb7N&md5=ef2f58f345103483f72ef3175ff6ace6CAS |
Moosdorf N, Renforth P, Hartmann J (2014) Carbon dioxide efficiency of terrestrial enhanced weathering. Environmental Science & Technology 48, 4809–4816.
| Carbon dioxide efficiency of terrestrial enhanced weathering.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC2cXjsVGrsLk%3D&md5=9508ef1ac48b6c2051ad047b3407d271CAS |
Mortvedt JJ (1995) Heavy metal contaminants in inorganic and organic fertilizers. Nutrient Cycling in Agroecosystems 43, 55–61.
Nahmani J, Hodson ME, Black S (2007) A review of studies performed to assess metal uptake by earthworms. Environmental Pollution 145, 402–424.
| A review of studies performed to assess metal uptake by earthworms.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28Xht1KgtbnF&md5=08f66c5da0f05d13e182ff151c045212CAS |
Nesbitt HW, Skinner WM (2001) Early development of Al, Ca, and Na compositional gradients in labradorite leached in pH 2 HCl solutions. Geochimica et Cosmochimica Acta 65, 715–727.
| Early development of Al, Ca, and Na compositional gradients in labradorite leached in pH 2 HCl solutions.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3MXhs1SrurY%3D&md5=5bd511354bdd91dc0109ed9e9abc637dCAS |
Nugent MA, Brantley SL, Pantano CG, Maurice PA (1998) The influence of natural mineral coatings on feldspar weathering. Nature 395, 588–591.
| The influence of natural mineral coatings on feldspar weathering.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK1cXms1artr8%3D&md5=573466ba5e056fd7d483868504f22ab6CAS |
Oelkers EH, Valsami-Jones E (2008) Phosphate mineral reactivity and global sustainability. Elements 4, 83–87.
| Phosphate mineral reactivity and global sustainability.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXmvV2rt7g%3D&md5=82b325283b4d50879f5e45284ffb52baCAS |
Ogunleye PO, Mayaki MC, Amapu IY (2002) Radioactivity and heavy metal composition of Nigerian phosphate rocks: possible environmental implications. Journal of Environmental Radioactivity 62, 39–48.
| Radioactivity and heavy metal composition of Nigerian phosphate rocks: possible environmental implications.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38XksFyrurY%3D&md5=13b399f8159dab7e69cf1868e536539eCAS |
Palandri JL, Kharaka YK (2004) ‘A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling.’ (Geological Survey: Menlo Park, CA)
Pantelica AI, Salagean MN, Georgescu II, Pincovschi ET (1997) INAA of some phosphates used in fertilizer industries. Journal of Radioanalytical and Nuclear Chemistry 216, 261–264.
| INAA of some phosphates used in fertilizer industries.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK2sXktFKmsLg%3D&md5=d6fd52e0fbca41de36d5ebfac315308dCAS |
Rajan SSS, Fox RL, Saunders WMH, Upsdell M (1991) Influence of pH, time and rate of application on phosphate rock dissolution and availability to pastures. Nutrient Cycling in Agroecosystems 28, 85–93.
Ramezanian A, Dahlin AS, Campbell CD, Hillier S, Mannerstedt-Fogelfors B, Öborn I (2013) Addition of a volcanic rockdust to soils has no observable effects on plant yield and nutrient status or on soil microbial activity. Plant and Soil 367, 419–436.
| Addition of a volcanic rockdust to soils has no observable effects on plant yield and nutrient status or on soil microbial activity.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3sXovFCltLg%3D&md5=8983e00266259f26989b8c0da48e6adaCAS |
Ramos CG, Querol X, Oliveira MLS, Pires K, Kautzmann RM, Oliveira LFS (2015) A preliminary evaluation of volcanic rock powder for application in agriculture as soil a remineralizer. The Science of the Total Environment 512–513, 371–380.
| A preliminary evaluation of volcanic rock powder for application in agriculture as soil a remineralizer.Crossref | GoogleScholarGoogle Scholar |
Renforth P (2012) The potential of enhanced weathering in the UK. International Journal of Greenhouse Gas Control 10, 229–243.
| The potential of enhanced weathering in the UK.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC38XhtlaksbjE&md5=1ac54a9d356f37f6bfaeb9488b742b64CAS |
Sabiha-Javied , Mehmood T, Chaudhry MM, Tufail M, Irfan N (2009) Heavy metal pollution from phosphate rock used for the production of fertilizer in Pakistan. Microchemical Journal 91, 94–99.
| Heavy metal pollution from phosphate rock used for the production of fertilizer in Pakistan.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXhsVyku77L&md5=3bc9011a7939d23da108fab53a2dd724CAS |
Schnoor JL (1990) Kinetics of chemical weathering: a comparison of laboratory and field weathering rates. In ‘Aquatic chemical kinetics’. (Ed. W Stumm) pp. 475–504. (John Wiley & Sons Inc.: New York)
Barral MT, Hermo BS, García-Rodeja E, Freire NV (2005) Reutilization of granite powder as an amendment and fertilizer for acid soils. Chemosphere 61, 993–1002.
| Reutilization of granite powder as an amendment and fertilizer for acid soils.Crossref | GoogleScholarGoogle Scholar |
Sizmur T, Hodson ME (2009) Do earthworms impact metal mobility and availability in soil?–a review. Environmental Pollution 157, 1981–1989.
| Do earthworms impact metal mobility and availability in soil?–a review.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXlsVKlsrw%3D&md5=0226b160210d5cd90271e6754c1c53f3CAS |
Stamford NP, Lima RA, Lira MA, Santos CRS (2008) Effectiveness of phosphate and potash rocks with Acidithiobacillus on sugarcane yield and their effects on soil chemical attributes. World Journal of Microbiology & Biotechnology 24, 2061–2066.
| Effectiveness of phosphate and potash rocks with Acidithiobacillus on sugarcane yield and their effects on soil chemical attributes.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXhtVWgu77J&md5=2ae6fc271e17c6870c923213f66acf03CAS |
Stumm W (1992) ‘Chemistry of the solid-water interface: processes at the mineral-water and particle-water interface in natural systems.’ (Wiley: Chichester)
Sverdrup H, Warfvinge P (1995) Estimating field weathering rates using laboratory kinetics. Reviews in Mineralogy and Geochemistry 31, 485–541.
Trolove S, Hedley M, Kirk G, Bolan N, Loganathan P (2003) Progress in selected areas of rhizosphere research on P acquisition. Soil Research 41, 471–499.
| Progress in selected areas of rhizosphere research on P acquisition.Crossref | GoogleScholarGoogle Scholar |
van Grinsven J, van Riemsdijk W (1992) Evaluation of batch and column techniques to measure weathering rates in soils. Geoderma 52, 41–57.
| Evaluation of batch and column techniques to measure weathering rates in soils.Crossref | GoogleScholarGoogle Scholar |
Van Kauwenbergh SJ, Stewart M, Mikkelsen R (2013) World reserves of phosphate rock: a dynamic and unfolding story. Better Crops with Plant Food 97, 18–20.
Van Straaten P (2002) ‘Rocks for crops: agrominerals of sub-Saharan Africa.’ (Icraf Nairobi: Kenya)
Van Straaten P (2006) Farming with rocks and minerals: challenges and opportunities. Anais da Academia Brasileira de Ciencias 78, 731–747.
| Farming with rocks and minerals: challenges and opportunities.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXkslWjtro%3D&md5=2679eb210bf45ecfdafcaad2f8a42050CAS |
Velbel MA (1993) Constancy of silicate-mineral weathering-rate ratios between natural and experimental weathering: implications for hydrologic control of differences in absolute rates. Chemical Geology 105, 89–99.
| Constancy of silicate-mineral weathering-rate ratios between natural and experimental weathering: implications for hydrologic control of differences in absolute rates.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK3sXitlOrsr0%3D&md5=87995ed7b98e1d78489700683c5e9b42CAS |
von Wilpert K, Lukes M (2003) Ecochemical effects of phonolite rock powder, dolomite and potassium sulfate in a spruce stand on an acidified glacial loam. Nutrient Cycling in Agroecosystems 65, 115–127.
| Ecochemical effects of phonolite rock powder, dolomite and potassium sulfate in a spruce stand on an acidified glacial loam.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXntl2ltQ%3D%3D&md5=0b8f3fa04fccf3f0c9ef8fb8659cd1f7CAS |
White AF, Brantley SL (2003) The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field? Chemical Geology 202, 479–506.
| The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field?Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXpsFeksbg%3D&md5=5c6944b71eb3c9585795d2dba5253d3dCAS |
Zhu C (2005) In situ feldspar dissolution rates in an aquifer. Geochimica et Cosmochimica Acta 69, 1435–1453.
| In situ feldspar dissolution rates in an aquifer.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXis1eltr8%3D&md5=bfa45cc8aa2985c18bbcf8f3194b10eeCAS |
Zhu C, Blum AE, Veblen DR (2004a) Feldspar dissolution rates and clay precipitation in the Navajo aquifer at Black Mesa, Arizona, USA. In ‘Water-rock interaction’. (Eds RB Wanty, RRI Seal) pp. 895–899. (A.A. Balkema: Saratoga Springs, New York)
Zhu C, Blum AE, Veblen DRD (2004b) A new hypothesis for the slow feldspar dissolution in groundwater aquifers. Geochimica et Cosmochimica Acta 68, A148
Zhu C, Veblen DR, Blum AE, Chipera SJ (2006) Naturally weathered feldspar surfaces in the Navajo Sandstone aquifer, Black Mesa, Arizona: Electron microscopic characterization. Geochimica et Cosmochimica Acta 70, 4600–4616.
| Naturally weathered feldspar surfaces in the Navajo Sandstone aquifer, Black Mesa, Arizona: Electron microscopic characterization.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XpsFykurk%3D&md5=e521e1288420dc73dc47b9a127d4fb40CAS |
Zhu C, Lu P, Zheng Z, Ganor J (2010) Coupled alkali feldspar dissolution and secondary mineral precipitation in batch systems: 4. Numerical modeling of kinetic reaction paths. Geochimica et Cosmochimica Acta 74, 3963–3983.
| Coupled alkali feldspar dissolution and secondary mineral precipitation in batch systems: 4. Numerical modeling of kinetic reaction paths.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3cXnt12ntrg%3D&md5=bd15a322f0ba3f2d6c5a8797b735cebcCAS |
Zhu C, Liu Z, Zhang Y, Wang C, Scheafer A, Lu P, Zhang G, Georg RB, Yuan HL, Rimstidt JD (2016) Measuring silicate mineral dissolution rates using Si isotope doping. Chemical Geology 445, 146–163.
| Measuring silicate mineral dissolution rates using Si isotope doping.Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC28XktVegtr0%3D&md5=adae62275d9fe83c317cff76dfb4c519CAS |