Evaluation of humic and fulvic acid extracts of compost, oilcake, and soils on complex formation with arsenic
K. Ghosh A , I. Das A B , D. K. Das A and S. K. Sanyal A
+ Author Affiliations
- Author Affiliations
A Department of Agricultural Chemistry and Soil Science, Bidhan Chandra Krishi Viswavidyalaya, Mohanpur, Nadia, West Bengal – 741 252, India.
B Corresponding author. Email: dasindra@rediffmail.com; indra26july@gmail.com
Soil Research 50(3) 239-248 https://doi.org/10.1071/SR12037
Submitted: 21 August 2011 Accepted: 14 March 2012 Published: 7 May 2012
Abstract
Fulvic acid (FA) and humic acid (HA) were extracted from compost, oilcake, and surface soils collected from arsenic-contaminated and uncontaminated sites of West Bengal. These HA/FA samples were characterised by pH–potentiometric titrations, viscometric measurements, visible spectrophotometry, and surface tension determinations. The results were correlated with coiling–decoiling behaviour, as well as aliphatic/aromatic balance of HA/FAs. The stability constant (logK) of the complexes formed by the natural HA/FA fractions of the given soils were quite stable, and the HA/FA fractions of the organic manures with arsenate in aqueous phases suggested the dependence of such complexation on the nature and properties of the humic polymers, which, in turn, would affect the retention/release of arsenate in soil.
The release potential of arsenic from the arsenate–HA/FA complexes by soluble sulfate and nitrate salts was also examined in terms of the appropriate exchange isotherms. In general, sulfate demonstrated a moderately greater degree of exchangeability with arsenate than did nitrate, at higher concentrations.
Additional keywords: isotherms, organic manure, soil extraction, humic/fulvic-arsenate complex, stability constant.
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