Surface ozone profiles at selected South Pacific sites

Abstract

Surface ozone profiles were studied at Fiji (18.1^oS, 178.2^oE), Samoa (14.3^oS, 170.6^oW), Tahiti (18.0^oS, 149.0^oW), and San Cristobal, Galapagos (0.9^oS, 89.6^oW) from 1997-2003. Surface ozone levels at these Pacific sites showed a wintertime maximum and a summertime minimum with the lowest mixing ratios occurring at Tahiti and Galapagos, while the highest mixing ratios occurred at Fiji. The seasonal trends at each site were found to be dependent on the varying photochemical sink strength and the changing transport regimes in each season. It was established that the reduced photochemical sink strength in winter was one of the major reasons for the observed increase in surface ozone levels at each site in that season. The presence of the South Pacific Convergence Zone particularly for the Western Pacific (Fiji, Samoa and Tahiti) is the other factor contributing to the observed seasonality and variability in surface ozone levels. The changing frequency of transport from the southern mid-latitude (from high altitudes) is the only transport regime at the boundary layer having the most significant influence on the surface ozone levels at these Pacific sites.