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RESEARCH ARTICLE
Contents Vol 72(11)

An Anionic Calcium Metal–Organic Framework Encapsulated with TbIII Ions as a Recyclable Luminescent Sensor for CrIII and FeIII Ions

Min Chen A C and Wen-Ming Xu B
+ Author Affiliations
- Author Affiliations

A Hubei University of Education, Hubei Key Laboratory of Purification and Application of Plant Anti-Cancer Active Ingredients, Wuhan, Hubei 430205, China.

B Zhengzhou University of Light Industry, Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou, Henan 450002, China.

C Corresponding author. Email: chem_chenmin@163.com

Australian Journal of Chemistry 72(11) 910-915 https://doi.org/10.1071/CH19197
Submitted: 3 May 2019  Accepted: 1 August 2019   Published: 4 September 2019

Abstract

A 3D CaII-based anionic metal–organic framework (Ca-MOF) with microporous pores containing [(CH3)2NH2]I cations has been synthesised. The Ca-MOF possesses a formula of [(CH3)2NH2]2[Ca5(TATB)4(DMA)4](DMA)10(H2O)2 (H3TATB = 4,4′,4″-s-triazine-2,4,6-triyltribenzoic acid, DMA = N,N-dimethylacetamide) with 12-connected [Ca5(O2CR)10] secondary building units and 3-connected TATB ligands to give a rare 12,3-connected net of llj topology. Furthermore, the postsynthetic material (TbIII@Ca-MOF), which is obtained by ion-exchange processes, exhibits an excellent ability for the recyclable detection of CrIII and FeIII ions.


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