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RESEARCH FRONT
Contents Vol 62(4)

Phosphonium-Based Ionic Liquids: An Overview

Kevin J. Fraser A and Douglas R. MacFarlane A B
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A School of Chemistry, Monash University, Wellington, VIC 3800, Australia.

B Corresponding author. Email: Douglas.Macfarlane@sci.monash.edu.au




Kevin J. Fraser received his M.Sc. in 2004 from the University of Aberdeen, Scotland. He recently completed his Ph.D. under the supervision of Professor D. R. MacFarlane entitled ‘Physical Properties of Phosphonium Based Ionic Liquids’ at Monash University, Melbourne. His current interests include air electrodes for use in fuel cells and ionic liquid-based chemical sensors.


Professor Doug MacFarlane leads the Monash Ionic Liquids Group at Monash University. He is also the program leader of the Energy Program in the Australian Centre for Electromaterials Science. He was a Ph.D. graduate of Purdue University in 1982 and after postdoctoral work at Victoria University Wellington took up a faculty position at Monash University. Professor MacFarlane was recently awarded an Australian Research Council Federation Fellowship to extend his work on Ionic Liquids. He was elected to the Australian Academy of Sciences in 2007. His research interests include the chemistry and properties of ionic liquids and solids and their application in a wide range of technologies from electrochemical (batteries, fuel cells, solar cells and corrosion prevention), to biotechnology (drug ionic liquids and protein stabilisation) and biofuel processing.

Australian Journal of Chemistry 62(4) 309-321 https://doi.org/10.1071/CH08558
Submitted: 19 December 2008  Accepted: 9 March 2009   Published: 24 April 2009

Abstract

Phosphonium cation-based ionic liquids (ILs) are a readily available family of ILs that in some applications offer superior properties as compared to nitrogen cation-based ILs. Applications recently investigated include their use as extraction solvents, chemical synthesis solvents, electrolytes in batteries and super-capacitors, and in corrosion protection. At the same time the range of cation–anion combinations available commercially has also been increasing in recent years. Here, we provide an overview of the properties of these interesting materials and the applications in which they are appearing.


Acknowledgements

The authors thank Dr Al Robertson of Cytec Industries Inc. for his valuable insights and helpful comments. D.R.M. is grateful to the Australian Research Council for a Federation Fellowship.


References


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