Free Standard AU & NZ Shipping For All Book Orders Over $80!
Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Construction of the 1,2,3,4-Tetrahydro-1,4,6,2-oxathiazaphosphorine Ring System

Wynona M. Johnson A B and Kathleen A. Turner A
+ Author Affiliations
- Author Affiliations

A CSIRO Molecular and Health Technologies, Clayton South VIC 3169, Australia.

B Corresponding author. Email: noni.johnson@csiro.au

Australian Journal of Chemistry 58(12) 834-836 https://doi.org/10.1071/CH05190
Submitted: 16 August 2005  Accepted: 21 October 2005   Published: 20 December 2005

Abstract

The novel 1,2,3,4-tetrahydro-1,4,6,2-oxathiazaphosphorine ring system has been prepared by reaction of the sodium salt of diethyl mercaptomethylphosphonate with nitrile oxides, followed by cyclization of the resulting hydroximinoyl sulfide. The stability of the new ring system is investigated.


References


[1]   W. M. Johnson, A. Faux, G. Fallon, Heterocycles 1999, 51,  2479.
         
         open url image1




* This reaction was not investigated under the specific conditions ultimately used to provide the oxathiazaphosphorines 6.

A molecular ion was not observed for this compound.

This compound was unstable to EI conditions so we were unable to obtain HRMS data.