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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Plasma/Corona Treatment of Silicones

Michael J. Owen A
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A Michigan Molecular Institute, 1910 West St. Andrews Road, Midland, MI 48640, USA.
Email: michaelowen01@chartermi.net

Australian Journal of Chemistry 58(6) 433-436 https://doi.org/10.1071/CH04297
Submitted: 18 December 2004  Accepted: 19 February 2005   Published: 14 June 2005

Abstract

There is considerable current interest in plasma and corona treatment of silicones. It is well established that a thin, silica-like layer is created on the surface by such treatments. Much fresh insight has emerged concerning the role of low-molecular-weight materials in the hydrophobic recovery of treated elastomers. Even if these diffusible species are removed before treatment, hydrophobic recovery still occurs above a threshold energy implying that they are produced in situ by the treatment. A particularly significant new direction in the plasma treatment field is plasma polymerization of organosilicon monomers using atmospheric pressure glow discharge (APGD).


I am indebted to Andy Goodwin, Stuart Leadley, and Lesley-Ann O’Hare of Dow Corning Plasma Solutions (Cork, Eire) and Jongsoo Kim and Manoj Chaudhury of Lehigh University (Bethlehem PA, USA) for their many contributions to these plasma/corona studies.


References


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