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RESEARCH ARTICLE
Contents Vol 75(9)

Monometallic Ln3+ and heterometallic Ln3+–Cd2+complexes based on pentafluorophenylacetic acid: efficient control of dimension and luminescent properties†

Y. A. Belousov https://orcid.org/0000-0002-4976-4437 A B * , M. A. Kiskin C , A. V. Sidoruk A , E. A. Varaksina B , M. A. Shmelev C , N. V. Gogoleva C , I. V. Taydakov B D and I. L. Eremenko C
+ Author Affiliations
- Author Affiliations

A Chemistry Department, Moscow State University, Leninskie Gory, Moscow 119991, Russia.

B P. N. Lebedev Physical Institute of Russian Academy of Sciences, Moscow 119991, Russia.

C Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.

D G. V. Plekhanov Russian University of Economics, Moscow 117997, Russia.

* Correspondence to: belousov@inorg.chem.msu.ru

Handling Editor: George Koutsantonis

Australian Journal of Chemistry 75(9) 572-580 https://doi.org/10.1071/CH21333
Submitted: 15 December 2021  Accepted: 6 January 2022   Published: 14 February 2022

© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing.

Abstract

Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent 1D coordination polymer, while the isostructural complexes 3 and 4 are molecular compounds. Complexes 1–4 show strong lanthanide-centred luminescence, since the introduction of phenanthroline leads to a significant increase in the observed lifetime (τobs) and photoluminescent quantum yield.

Keywords: cadmium, carboxylates, carboxylic acids, crystal structure, europium, lanthanides, luminescence, MOF, terbium.


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