Synthesis and luminescent properties of heteroleptic lanthanide complexes with oxybenzo[h]quinoline
Tatyana V. Balashova
A , Svetlana K. Polyakova A , Vasily A. Ilichev A , Andrey A. Kukinov A , Roman V. Rumyantcev A , Georgy K. Fukin A , Artem N. Yablonskiy B and Mikhail N. Bochkarev A *
+ Author Affiliations
- Author Affiliations
A G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina Street, 49, 603950 Nizhny Novgorod, Russian Federation.
B Institute for Physics of Microstructures of Russian Academy of Sciences, Akademicheskaya Street 7, 603950 Nizhny Novgorod, Russian Federation.
Australian Journal of Chemistry 75(9) 532-542 https://doi.org/10.1071/CH21279
Submitted: 26 October 2021 Accepted: 10 December 2021 Published: 9 February 2022
© 2022 The Author(s) (or their employer(s)). Published by CSIRO Publishing.
Abstract
The heteroligand complexes CpLn(BQ)2(DME) (BQ = 10-oxybenzo[h]quinoline, Cp = cyclopentadienyl, Ln = La (1), Nd (2), Sm (3), Gd (4)) were synthesised by the reaction of Cp3Ln with (BQ)H. The complexes of La, Nd and Sm were structurally characterised. In the case of ytterbium the reaction affords Cp2Yb(BQ)(DME) (5) and homoligand binuclear complex Yb2(BQ)6 (6) iregardless of the molar ratio of initial reagents. Upon UV excitation all the complexes gave rise to fluorescence of ligands in the visible region. The photoluminescent spectrum of compound 1 also contains a phosphorescent band with a lifetime longer than 10 ms. The complexes of Nd, Sm and Yb along with ligand emission display metal-centered luminescent f–f transitions.
Keywords: 10-hydroxybenzo[h]quinoline, coordination chemistry, energy transfer, fluorescence, heteroligand complexes, lanthanides, luminescence, phosphorescence, X-ray structure.
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