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RESEARCH ARTICLE
Contents Vol 73(12)

Synthesis, Characterization, and Theoretical Studies of cis-Dichloridobis(8-quinolinethiolato)tin(iv) and bis(8-Sulfanylquinolinium) Hexachloridostannate(iv) Derivatives*

Rajesh Deka https://orcid.org/0000-0002-9460-1784 A B C , Arup Sarkar https://orcid.org/0000-0002-6880-8220 A , Harkesh B. Singh https://orcid.org/0000-0002-0403-0149 A B E , Peter C. Junk https://orcid.org/0000-0002-0683-8918 B D , David R. Turner https://orcid.org/0000-0003-1603-7994 B C E and Glen B. Deacon https://orcid.org/0000-0002-6966-6121 B C
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400076, India.

B IITB-Monash Research Academy, Mumbai 400076, India.

C School of Chemistry, Monash University, Clayton, Vic. 3800, Australia.

D College of Science and Engineering, James Cook University, Townsville, Qld 4811, Australia.

E Corresponding authors. Email: chhbsia@chem.iitb.ac.in; david.turner@monash.edu

Australian Journal of Chemistry 73(12) 1128-1137 https://doi.org/10.1071/CH19561
Submitted: 28 October 2019  Accepted: 16 February 2020   Published: 7 July 2020

Abstract

The structural characterisation of bis(8-sulfanylquinolinium) hexachloridostannate(iv) (2) is reported and the variable reaction behaviour of this compound in different solvents has been explored. In particular, attempted recrystallization of 2 from chloroform and dichloromethane affords two polymorphs of cis-dichloridobis(8-quinolinethiolato)tin(iv), 3m and 3t, respectively. Attempted recrystallization of 2 from methanol gives crystals of 8,8′-dithiodiquinolinium hexachloridostannate(iv) 4. When 2 is dissolved in dimethyl sulfoxide in the presence of air, it undergoes oxidation to afford diquinolinyl-8,8′-disulfide 5. The molecular structures of the isolated compounds 2–4 are unambiguously authenticated by single crystal X-ray diffraction studies. The electronic structure properties of all the isolated compounds 2–4 are thoroughly studied by DFT calculations.


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