Zinc-Containing Coordination Polymer as a Suitable Precursor for Solid State Synthesis of ZnO
Maryam Mohammadikish A C , Zohreh Zafari A and Susan Torabi BA Faculty of Chemistry, Kharazmi University, Tehran 15719-14911, Iran.
B Deputy of Food and Drug Control, Shiraz University of Medical Science, Shiraz 71345, Iran.
C Corresponding author. Email: mohammadikish@khu.ac.ir
Australian Journal of Chemistry 72(9) 693-698 https://doi.org/10.1071/CH19026
Submitted: 23 January 2019 Accepted: 23 May 2019 Published: 21 June 2019
Abstract
Uniform zinc-containing infinite coordination polymer (ICP) nanoparticles were achieved via a straightforward and rapid precipitation method in 5 min, from a bi-thioglycolate functionalized salpn ligand (salpn = N,N′-bis(salicylidene)-1,3-propanediamine) as linker and zinc acetate. Characterization of the resulting product was performed by CHN elemental analysis, inductively coupled plasma–optical emission spectroscopy, FT-IR spectroscopy, thermogravimetric analysis, electron microscopies (FE-SEM and HR-TEM), and photoluminescence spectroscopy. Elemental analyses verified the proposed structure for the ICP with a 1 : 2 ratio of the salpn type ligand and Zn2+ ion. FE-SEM, TEM, and AFM analyses unveiled the existence of nanoparticles with diameters of ~30 nm. PL spectroscopy showed a blue shift in emission peak of the ICP with regards to the organic ligand. The obtained ICP was utilized as a precursor to synthesize ZnO nanoparticles with wurtzite structure. An increase in bandgap of the prepared ZnO nanoparticles was observed in comparison with bulk ZnO as a result of quantum confinement of photogenerated electron–hole pairs. This method can be exploited for the synthesis of other coordination polymer micro/nanostructures.
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