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RESEARCH ARTICLE
Contents Vol 70(3)

Preparation of CoWO4/g-C3N4 and its Ultra-Deep Desulfurization Property

Pengfei Xing A , Rongxiang Zhao A B , Xiuping Li A and Xiaohan Gao A
+ Author Affiliations
- Author Affiliations

A College of Chemistry, Chemical Engineering and Environment Engineering, Liaoning Shihua University, Fushun 113001, China.

B Corresponding author. Email: zylhzrx@126.com

Australian Journal of Chemistry 70(3) 271-279 https://doi.org/10.1071/CH16320
Submitted: 25 May 2016  Accepted: 6 August 2016   Published: 8 September 2016

Abstract

The ultra-deep desulfurization of fuel oil has become inevitable for environmental protection. Here, CoWO4/g-C3N4 was used as a catalyst, H2O2 as an oxidant, and 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM][EtSO4], IL) as an extractant for the oxidative desulfurization of model oil. Scanning electron microscopy, FT-IR spectroscopy, N2 adsorption isotherms, and X-ray diffraction were used to confirm the morphology, structure, and properties of the catalysts. The influence of calcination temperature, loading dose of cobalt, amount of H2O2, reaction temperature, and other parameters were investigated. The removal rate of sulfide in model oil could reach 92.9 % at 80°C in 180 min under the optimal operation conditions (V(oil) = 5 mL, T = 80°C, m(catalyst) = 0.03 g, V(H2O2) = 0.4 mL, t = 180 min, V(IL) = 1.0 mL). In addition, the catalyst was reused five times with no significant reduction in the catalytic activity.


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