Functionalised 1-Alkynylarsines: Synthesis, Characterisation, and Attempts of Rearrangement into Functionalised Arsaalkynes*
Gnon Baba A B and Jean-Claude Guillemin A CA Institut des Sciences Chimiques de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, UMR6226, 11 Allée de Beaulieu, CS 50837, 35708 Rennes Cedex 7, France.
B Laboratoire d’Assainissement, Sciences de l’Eau et Environnement (LASEE), Faculté des Sciences et Techniques, Université de Kara, B.P. 404, Kara, Togo.
C Corresponding author. Email: jean-claude.guillemin@ensc-rennes.fr
Australian Journal of Chemistry 67(9) 1357-1359 https://doi.org/10.1071/CH14176
Submitted: 28 March 2014 Accepted: 30 April 2014 Published: 3 June 2014
Abstract
Functionalised 1-alkynylarsines were synthesised by reaction of the corresponding 1-alkynyltributylstannane on arsenic trichloride followed by chemoselective reduction of the formed 1-alkynyldichloroarsine by tributyltin hydride in the presence of small amounts of a radical inhibitor. Rearrangements of these compounds into the corresponding arsaalkynes were attempted.
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