Synthesis, Structures, and Conformations of Linked Bis-Glyoxylamides Derived from Bis-Acylisatins
Venty Suryanti A B , Glenn C. Condie A , Mohan Bhadbhade C , Roger Bishop A , David StC. Black A D and Naresh Kumar A D
+ Author Affiliations
- Author Affiliations
A School of Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia.
B Current address: Department of Chemistry, The University of Sebelas Maret, Surakarta, Jawa Tengah 57126, Indonesia.
C Mark Wainwright Analytical Centre, The University of New South Wales, Sydney, NSW 2052, Australia.
D Corresponding authors. Email: d.black@unsw.edu.au; n.kumar@unsw.edu.au
Australian Journal of Chemistry 67(9) 1270-1278 https://doi.org/10.1071/CH14135
Submitted: 11 March 2014 Accepted: 16 April 2014 Published: 19 May 2014
Abstract
A series of bis-glyoxylamides possessing hydrophobic alkyl chains was successfully synthesised by ring opening of bis-acylisatins with amines or amino acid alkyl esters. The crystal structures revealed the interplay of intra- and intermolecular interactions (NH···O and C=O···C=O interactions) and the conformations of these long molecules.
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