Syntheses, Crystal Structures, and Properties of Six Coordination Complexes Based on a Newly Designed Mercapto-thiadiazole Ligand

Lu-Lu Wei; Lin-Ke Li; Li-Yan Fan; Chang-Hong Wang; Hong-Wei Hou

doi:10.1071/CH13417

RESEARCH ARTICLE

Previous Next Contents Vol 67(2)

Syntheses, Crystal Structures, and Properties of Six Coordination Complexes Based on a Newly Designed Mercapto-thiadiazole Ligand

Lu-Lu Wei ^A , Lin-Ke Li ^A ^B , Li-Yan Fan ^A , Chang-Hong Wang ^A and Hong-Wei Hou ^A ^B

+ Author Affiliations

- Author Affiliations

^A The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China.

^B Corresponding authors. Email: lilinke@zzu.edu.cn; houhongw@zzu.edu.cn

Australian Journal of Chemistry 67(2) 241-249 https://doi.org/10.1071/CH13417
Submitted: 14 August 2013 Accepted: 16 September 2013 Published: 17 October 2013

Abstract

Six coordination complexes were solvothermally synthesised: a 3D framework [Cd(tmtt)₂]_n (1), 2D architectures [Zn(tmtt)₂]_n (2) and [Pb(tmtt)₂]_n (3), 1D chain structures [Ni(tmtt)₂·(H₂O)₂]_n (4) and [Co(tmtt)₂·(H₂O)₂]_n (5), and a mononuclear structure [Hg(tmtt)₂] (6). The complexes, based on self-assembly of different metal ions with a newly designed mercapto-thiadiazole ligand tmttH (tmttH = 5-[(1H-1,2,4-triazol-1-yl)methyl]-1,3,4-thiadiazole-2(3H)-thione), were characterised by single crystal X-ray diffraction analyses. Crystal structure analyses reveal that complex 1 exhibits a four-fold interpenetrating 3D framework with {6⁴.8²} topology based on two kinds of right-handed single-helical chains, 2 displays a bilayer structure, 3 presents a crown-shaped network, 4 and 5 show 1D double–helical chain structures, and 6 is a mononuclear structure. Moreover, the thermal stabilities of crystalline samples 1–6 have been investigated, and the luminescent properties of complexes 1, 2, 3, 6, and the free ligand have been studied. The results of photoluminescent measurements illustrate that 2 and 3 may serve as excellent candidates for potential photoactive materials.

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