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Contents Vol 64(9)

MgII, CaII, and CoII Metal-Organic Framework Materials with [Si(p-C6H4CO2)3(p-C6H4CO2H)]3– Struts

Robert P. Davies A B , Paul D. Lickiss A B , Karen Robertson A and Andrew J. P. White A
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK.

B Corresponding authors. Email: r.davies@imperial.ac.uk; p.lickiss@imperial.ac.uk

Australian Journal of Chemistry 64(9) 1239-1246 https://doi.org/10.1071/CH11155
Submitted: 20 April 2011  Accepted: 16 June 2011   Published: 16 September 2011

Abstract

Three new metal-organic framework materials [Mg3(LH)2(EtOH)2(H2O)]·(EtOH)4.5(H2O)0.25 (IMP-13Mg), [Co3(LH)2(EtOH)2(H2O)]·(EtOH)3 (IMP-13Co), and [Ca3(LH)2(EtOH)4]·(EtOH)6 (IMP-14) have been prepared from the treatment of silanetetrabenzoic acid (L-H4) with MgII, CoII, and CaII salts respectively. In all cases the silanetetrabenzoic acid has been triply deprotonated and the resultant carboxylate groups assemble with trinuclear metal-based nodes to give (3,6)-connected kgd-type two-dimensional layers. These layers are then extended into the third dimension by coordination of the metal nodes by carboxylic acid groups in adjacent layers. In the case of IMP-13Mg/Co, only alternate L-H connectors and metal nodes are involved in these interlayer interactions, leaving some acid groups free within the structure. However, in IMP-14 all L-H connectors and metal nodes participate in interlayer bonding.


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