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RESEARCH FRONT
Contents Vol 63(7)

Matrix Isolation and Electronic Structure of Di- and Tridehydrobenzenes

Michael Winkler A B and Wolfram Sander A
+ Author Affiliations
- Author Affiliations

A Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, Universitätsstr. 150, 44780 Bochum, Germany.

B Corresponding author. Email: Michael.Winkler@rub.de

Australian Journal of Chemistry 63(7) 1013-1047 https://doi.org/10.1071/CH10113
Submitted: 9 March 2010  Accepted: 10 June 2010   Published: 15 July 2010

Abstract

Within the past four decades, matrix isolation spectroscopy has emerged as the method of choice for obtaining direct structural information on benzynes and related dehydroaromatics. In combination with quantum chemical computations, detailed insight into the structure and reactivity of di-, tri-, and tetradehydrobenzenes has been obtained. This Review focuses on rather recent developments in aryne chemistry with a special emphasis on the matrix isolation of tridehydrobenzenes and related systems.


Acknowledgement

Financial support by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie is gratefully acknowledged. M.W. thanks the Fonds der Chemischen Industrie for a Liebig fellowship.


References


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