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RESEARCH ARTICLE
Contents Vol 63(6)

A New 3D Metal–Organic Framework Containing Chelidamic Acid with Unusual (3,6)-Connected Topology: Synthesis, Crystal Structure, and Optical Properties

Jian-Ping Zou A B C , Ming-Jun Li A , Qiu-Ju Xing A , Zhen-Hai Wen A , Gui-Sheng Zeng A , Ai-Qing Zhang A , Qiang Peng A C and Guo-Cong Guo B
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Nondestructive Testing (Nanchang Hangkong University), Ministry of Education, Nanchang, Jiangxi 330063, China.

B State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

C Corresponding authors. Email: zjp_112@126.com; qiangpeng@tom.com

Australian Journal of Chemistry 63(6) 942-945 https://doi.org/10.1071/CH10082
Submitted: 12 February 2010  Accepted: 19 May 2010   Published: 11 June 2010

Abstract

A new metal–organic framework [(LaL)·3H2O]n (L = chelidamic acid) with good optical properties was obtained through the hydrothermal reaction. It is the third three-dimensional framework constructed from chelidamic acid and presents a rare (3,6)-connected topology with Schläfli symbol (42.6)2(44.62.87.102).


Acknowledgements

We gratefully acknowledge the financial support of the NSF of China (20801026), the NSF of Jiangxi Province (2008GQC0036), the Aviation Science Foundation of China (2008ZF56012), Foundation of State Key Laboratory of Structural Chemistry (20100015), and Open Fund of the Key Laboratory of Nondestructive Testing, Ministry of Education, Nanchang Hangkong University (ZD200929007).


References


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