An Octanuclear Iron(iii) Cluster Complex Containing the Nitroso Bridging Ligand Carbamoylcyanonitrosomethanide

Anthony S. R. Chesman; David R. Turner; Boujemaa Moubaraki; Keith S. Murray; Glen B. Deacon; Stuart R. Batten

doi:10.1071/CH09224

RESEARCH FRONT

An Octanuclear Iron(iii) Cluster Complex Containing the Nitroso Bridging Ligand Carbamoylcyanonitrosomethanide

Anthony S. R. Chesman ^A , David R. Turner ^A , Boujemaa Moubaraki ^A , Keith S. Murray ^A , Glen B. Deacon ^A and Stuart R. Batten ^A ^B

+ Author Affiliations

- Author Affiliations

^A School of Chemistry, Monash University, Wellington Road, Clayton, Vic. 3800, Australia.

^B Corresponding author. Email: stuart.batten@sci.monash.edu.au

Australian Journal of Chemistry 62(9) 1137-1141 https://doi.org/10.1071/CH09224
Submitted: 15 April 2009 Accepted: 3 June 2009 Published: 17 September 2009

Abstract

The synthesis, structure, and magnetism is reported for an antiferromagnetically coupled, disc-shaped cluster containing the anionic ligand carbamoylcyanonitrosomethanide (ccnm), [Fe₈O₆(MeO)₆(ccnm)₆], with an Fe^III₈O₃ core.

Acknowledgements

We thank the Australian Research Council for funding Discovery grants to S.R.B. and K.S.M. and for an Australian Postdoctoral Fellowship (D.R.T.). A.S.R.C. acknowledges an Australian Postgraduate Award.

References

An Octanuclear Iron(iii) Cluster Complex Containing the Nitroso Bridging Ligand Carbamoylcyanonitrosomethanide

Abstract

Acknowledgements

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